Tris(acetylacetonato) Iron(III): Recent Developments and Synthetic Applications
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Original version
Lübken, D.; Saxarra, M.; Kalesse, M.: Tris(acetylacetonato) Iron(III): Recent Developments and Synthetic Applications. In: Synthesis (Germany) 51 (2019), Nr. 1, S. 161-177. DOI:
https://doi.org/10.1055/s-0037-1610393
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To cite the version in the repository, please use this identifier:
https://doi.org/10.15488/10508
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Abstract:
Tris(acetylacetonato) iron(III) [Fe(acac) 3 ] is an indispensable reagent in synthetic chemistry. Its applications range from hydrogen atom transfer to cross-coupling reactions and to use as a Lewis acid. Consequently, the exceptional utility of Fe(acac) 3 has been demonstrated in several total syntheses. This short review summarizes the applications of Fe(acac) 3 in methodology and catalysis and highlights its use for the synthesis of medicinally relevant structures and in natural product syntheses. 1 Introduction 2 Hydrogen Atom Transfer (HAT) 3 Oxidations and Radical Transformations 4 Synthesis and Use of Alkynes and Allenes 5 Cross-Couplings and Cycloisomerizations 6 Borylations 7 Miscellaneous Reactions 8 Conclusions. © 2018 Georg Thieme Verlag. All rights reserved.
License of this version:
CC BY-NC-ND 4.0 Unported -
https://creativecommons.org/licenses/by-nc-nd/4.0/
Publication type:
Article
Publishing status:
publishedVersion
Publication date:
2019
Keywords english:
catalysis
,
cross-couplings
,
Fe(acac) 3
,
hydrogen atom transfer
,
radical transformations
,
synthetic chemistry
,
tris(acetylacetonato) iron(III)
DDC:
540 | Chemie
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