Tris(acetylacetonato) Iron(III): Recent Developments and Synthetic Applications

Originalpublikation

Lübken, D.; Saxarra, M.; Kalesse, M.: Tris(acetylacetonato) Iron(III): Recent Developments and Synthetic Applications. In: Synthesis (Germany) 51 (2019), Nr. 1, S. 161-177. DOI: https://doi.org/10.1055/s-0037-1610393

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Zusammenfassung:
Tris(acetylacetonato) iron(III) [Fe(acac) 3 ] is an indispensable reagent in synthetic chemistry. Its applications range from hydrogen atom transfer to cross-coupling reactions and to use as a Lewis acid. Consequently, the exceptional utility of Fe(acac) 3 has been demonstrated in several total syntheses. This short review summarizes the applications of Fe(acac) 3 in methodology and catalysis and highlights its use for the synthesis of medicinally relevant structures and in natural product syntheses. 1 Introduction 2 Hydrogen Atom Transfer (HAT) 3 Oxidations and Radical Transformations 4 Synthesis and Use of Alkynes and Allenes 5 Cross-Couplings and Cycloisomerizations 6 Borylations 7 Miscellaneous Reactions 8 Conclusions. © 2018 Georg Thieme Verlag. All rights reserved.
Lizenzbestimmungen: CC BY-NC-ND 4.0 Unported - https://creativecommons.org/licenses/by-nc-nd/4.0/
Publikationstyp: Article
Publikationsstatus: publishedVersion
Erstveröffentlichung: 2019
Schlagwörter (englisch): catalysis, cross-couplings, Fe(acac) 3, hydrogen atom transfer, radical transformations, synthetic chemistry, tris(acetylacetonato) iron(III)
Fachliche Zuordnung (DDC): 540 | Chemie

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