dc.identifier.uri |
http://dx.doi.org/10.15488/3724 |
|
dc.identifier.uri |
https://www.repo.uni-hannover.de/handle/123456789/3758 |
|
dc.contributor.author |
Jepsen, Julian
|
|
dc.contributor.author |
Milanese, Chiara
|
|
dc.contributor.author |
Puszkiel, Julian
|
|
dc.contributor.author |
Girella, Alessandro
|
|
dc.contributor.author |
Schiavo, Benedetto
|
|
dc.contributor.author |
Lozano, Gustavo A.
|
|
dc.contributor.author |
Capurso, Giovanni
|
|
dc.contributor.author |
Von Colbe, José M. Bellosta
|
|
dc.contributor.author |
Marini, Amedeo
|
|
dc.contributor.author |
Kabelac, Stephan
|
|
dc.contributor.author |
Dornheim, Martin
|
|
dc.contributor.author |
Klassen, Thomas
|
|
dc.date.accessioned |
2018-09-21T12:30:24Z |
|
dc.date.available |
2018-09-21T12:30:24Z |
|
dc.date.issued |
2018 |
|
dc.identifier.citation |
Jepsen, J.; Milanese, C.; Puszkiel, J.; Girella, A.; Schiavo, B. et al.: Fundamental material properties of the 2LiBH4-MgH2 reactive hydride composite for hydrogen storage: (II) Kinetic properties. In: Energies 11 (2018), Nr. 5, 1170. DOI: https://doi.org/10.3390/en11051170 |
|
dc.description.abstract |
Reaction kinetic behaviour and cycling stability of the 2LiBH4-MgH2 reactive hydride composite (Li-RHC) are experimentally determined and analysed as a basis for the design and development of hydrogen storage tanks. In addition to the determination and discussion about the properties; different measurement methods are applied and compared. The activation energies for both hydrogenation and dehydrogenation are determined by the Kissinger method and via the fitting of solid-state reaction kinetic models to isothermal volumetric measurements. Furthermore, the hydrogen absorption-desorption cycling stability is assessed by titration measurements. Finally, the kinetic behaviour and the reversible hydrogen storage capacity of the Li-RHC are discussed. |
eng |
dc.language.iso |
eng |
|
dc.publisher |
Basel : MDPI AG |
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dc.relation.ispartofseries |
Energies 11 (2018), Nr. 5 |
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dc.rights |
CC BY 4.0 Unported |
|
dc.rights.uri |
https://creativecommons.org/licenses/by/4.0/ |
|
dc.subject |
Borohydrides |
eng |
dc.subject |
Hydrogen storage |
eng |
dc.subject |
LiBH4-MgH2 |
eng |
dc.subject |
Material properties |
eng |
dc.subject |
Metal hydrides |
eng |
dc.subject |
Reactive hydride composites |
eng |
dc.subject |
Activation energy |
eng |
dc.subject |
Hydrides |
eng |
dc.subject |
Kinetics |
eng |
dc.subject |
Lithium compounds |
eng |
dc.subject |
Magnesium compounds |
eng |
dc.subject |
Materials properties |
eng |
dc.subject |
Reaction kinetics |
eng |
dc.subject |
Solid state reactions |
eng |
dc.subject |
Borohydrides |
eng |
dc.subject |
Design and Development |
eng |
dc.subject |
Hydrogen storage capacities |
eng |
dc.subject |
Hydrogen storage tank |
eng |
dc.subject |
LiBH4-MgH2 |
eng |
dc.subject |
Measurement methods |
eng |
dc.subject |
Metal hydrides |
eng |
dc.subject |
Volumetric measurement |
eng |
dc.subject |
Hydrogen storage |
eng |
dc.subject.ddc |
530 | Physik
|
ger |
dc.title |
Fundamental material properties of the 2LiBH4-MgH2 reactive hydride composite for hydrogen storage: (II) Kinetic properties |
|
dc.type |
Article |
|
dc.type |
Text |
|
dc.relation.issn |
19961073 |
|
dc.relation.doi |
https://doi.org/10.3390/en11051170 |
|
dc.bibliographicCitation.issue |
5 |
|
dc.bibliographicCitation.volume |
11 |
|
dc.bibliographicCitation.firstPage |
1170 |
|
dc.description.version |
publishedVersion |
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tib.accessRights |
frei zug�nglich |
|