Fundamental material properties of the 2LiBH4-MgH2 reactive hydride composite for hydrogen storage: (II) Kinetic properties

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Jepsen, J.; Milanese, C.; Puszkiel, J.; Girella, A.; Schiavo, B. et al.: Fundamental material properties of the 2LiBH4-MgH2 reactive hydride composite for hydrogen storage: (II) Kinetic properties. In: Energies 11 (2018), Nr. 5, 1170. DOI: https://doi.org/10.3390/en11051170

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Abstract: 
Reaction kinetic behaviour and cycling stability of the 2LiBH4-MgH2 reactive hydride composite (Li-RHC) are experimentally determined and analysed as a basis for the design and development of hydrogen storage tanks. In addition to the determination and discussion about the properties; different measurement methods are applied and compared. The activation energies for both hydrogenation and dehydrogenation are determined by the Kissinger method and via the fitting of solid-state reaction kinetic models to isothermal volumetric measurements. Furthermore, the hydrogen absorption-desorption cycling stability is assessed by titration measurements. Finally, the kinetic behaviour and the reversible hydrogen storage capacity of the Li-RHC are discussed.
License of this version: CC BY 4.0
Document Type: article
Publishing status: publishedVersion
Issue Date: 2018
Appears in Collections:Fakultät für Maschinenbau

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1 image of flag of Germany Germany 18 85.71%
2 image of flag of Austria Austria 2 9.52%
3 image of flag of Spain Spain 1 4.76%

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