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Original version
Hotje, U.; Wartchow, R.; Binnewies, M.: Chemischer Transport fester Lösungen, 26 [1]. Untersuchungen zur Mischphasenbildung und zum chemischen Transport in den Systemen TiS 2/NbS 2, TiSe 2/NbSe 2, NbS 2/TaS 2 und NbSe 2/TaSe 2. In: Zeitschrift für Naturforschung - Section B Journal of Chemical Sciences 60 (2005), Nr. 12, S. 1241-1249. DOI: https://doi.org/10.1515/znb-2005-1205
Repository version
To cite the version in the repository, please use this identifier:
https://doi.org/10.15488/2385
Files in this item
| Abstract: | |
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In the systems TiS 2/NbS 2, TiSe 2/NbSe 2, NbS 2/TaS 2 und NbSe 2/TaSe 2 complete miscibility in the solid state has been observed by powder X-ray investigations. Mixed crystals as well as the binary compounds can be prepared by chemical vapour transport reactions using iodine as transport agent in the temperature gradient 1000 → 900°C. The gaseous species TiI 3(g), TiI 4(g), NbI 4(g) and TaI 4(g) are responsible for the transport effect. © 2005 Verlag der Zeitschrift für Naturforschung.
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| License of this version: | CC BY-NC-ND 3.0 Unported - https://creativecommons.org/licenses/by-nc-nd/3.0/ |
| Publication type: | Article |
| Publishing status: | publishedVersion |
| Publication date: | 2005 |
| Keywords english: | Chemical Vapour Transport (CVT), Mixed Crystals of Ti 1-xNb xS 2, Nb 1-xTa xS, Nb 1-xTa xSe 2, Ti 1-xNb xSe 2 |
| DDC: | 540 | Chemie |
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Naturwissenschaftliche Fakultät
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