Cohalogenation of Allyl and Vinylsilanes using Polymer-bound Haloate(I)-Reagents

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Domann, Silvie; Sourkouni-Argirusi, Georgia; Merayo, Nuria; Schönberger, Andreas; Kirschning, Andreas: Cohalogenation of Allyl and Vinylsilanes using Polymer-bound Haloate(I)-Reagents. In: Molecules 6 (2001), Nr. 1, S. 61-66. DOI: https://doi.org/10.3390/60100061

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To cite the version in the repository, please use this identifier: https://doi.org/10.15488/1564

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Abstract:
Polymer-supported electrophilic halogenate(I) complexes 2 and 3 promote smooth addition to vinyl and allylsilanes without loss of the silyl group. In conjunction with Amberlyst A26 (OH− -form) vinyl silanes are converted into epoxysilanes.
License of this version: CC BY-NC-SA 3.0 Unported - https://creativecommons.org/licenses/by-nc-sa/3.0/
Publication type: Article
Publishing status: publishedVersion
Publication date: 2001
Keywords english: allylsilane, cohalogenation, polymer-supported reagent, vinylsilane
DDC: 540 | Chemie

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