Hybrid catalysis for enantioselective Baeyer-Villiger oxidation and stereoselective epoxidation: a Cp*Ir complex to fuel FMN and FAD reduction for flavoprotein monooxygenase modules

Röllig, Robert; Paul, Caroline E.; Rousselot-Pailley, Pierre; Kara, Selin; Alphand, Véronique

dc.identifier.uri	http://dx.doi.org/10.15488/16255
dc.identifier.uri	https://www.repo.uni-hannover.de/handle/123456789/16382
dc.contributor.author	Röllig, Robert
dc.contributor.author	Paul, Caroline E.
dc.contributor.author	Rousselot-Pailley, Pierre
dc.contributor.author	Kara, Selin
dc.contributor.author	Alphand, Véronique
dc.date.accessioned	2024-02-09T07:53:51Z
dc.date.available	2024-02-09T07:53:51Z
dc.date.issued	2023
dc.identifier.citation	Röllig, R.; Paul, C.E.; Rousselot-Pailley, P.; Kara, S.; Alphand, V.: Hybrid catalysis for enantioselective Baeyer-Villiger oxidation and stereoselective epoxidation: a Cp*Ir complex to fuel FMN and FAD reduction for flavoprotein monooxygenase modules. In: Reaction Chemistry & Engineering 12 (2023), S. 3117-3123. DOI: https://doi.org/10.1039/d3re00411b
dc.description.abstract	Taking advantage of the unique properties of two-component flavo-monooxygenases and the ability of [Cp*Ir(bpy-OMe)H]+ to transfer hydrides to reduce flavins, we extended the scope of the pH- and oxygen-robust iridium(iii)-complex to drive the enzymatic reaction of a FMN-dependent Baeyer-Villiger monooxygenase and a FAD-dependent styrene monooxygenase (respectively FPMO Group C and E), using formic acid as H-donor for NADH recycling.	eng
dc.language.iso	eng
dc.publisher	Cambridge : Royal Society of Chemistry
dc.relation.ispartofseries	Reaction Chemistry & Engineering 12 (2023)
dc.rights	CC BY-NC 3.0 Unported
dc.rights.uri	https://creativecommons.org/licenses/by-nc/3.0
dc.subject	Iridium compounds	eng
dc.subject	% reductions	eng
dc.subject	Baeyer Villiger oxidation	eng
dc.subject	Enantioselective	eng
dc.subject	Enzymatic reaction	eng
dc.subject	Ir complexes	eng
dc.subject	Iridium complex	eng
dc.subject	Monooxygenases	eng
dc.subject	Property	eng
dc.subject	Stereo-selective	eng
dc.subject	Two-component	eng
dc.subject	Styrene	eng
dc.subject.ddc	540 \| Chemie
dc.title	Hybrid catalysis for enantioselective Baeyer-Villiger oxidation and stereoselective epoxidation: a Cp*Ir complex to fuel FMN and FAD reduction for flavoprotein monooxygenase modules	eng
dc.type	Article
dc.type	Text
dc.relation.essn	2058-9883
dc.relation.doi	https://doi.org/10.1039/d3re00411b
dc.bibliographicCitation.volume	12
dc.bibliographicCitation.firstPage	3117
dc.bibliographicCitation.lastPage	3123
dc.description.version	publishedVersion	eng
tib.accessRights	frei zug�nglich