Taming Bromine Azide for Use in Organic Solvents─Radical Bromoazidations and Alcohol Oxidations

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dc.identifier.uri http://dx.doi.org/10.15488/14786
dc.identifier.uri https://www.repo.uni-hannover.de/handle/123456789/14905
dc.contributor.author Schulz, Göran
dc.contributor.author George, Vincent
dc.contributor.author Taser, Daghan
dc.contributor.author Kirschning, Andreas
dc.date.accessioned 2023-09-19T08:26:28Z
dc.date.available 2023-09-19T08:26:28Z
dc.date.issued 2023
dc.identifier.citation Schulz, G.; George, V.; Taser, D.; Kirschning, A.: Taming Bromine Azide for Use in Organic Solvents─Radical Bromoazidations and Alcohol Oxidations. In: Journal of Organic Chemistry, The 88 (2023), Nr. 6, S. 3781-3786. DOI: https://doi.org/10.1021/acs.joc.2c03012
dc.description.abstract The formation of bromine azide from the bisazidobromate(I) anion or alternatively from Zhdankin’s reagent, using a phosphonium bromide salt as a common starting point, is reported. After homolytic cleavage in the presence of alkenes or alcohols either 1,2-functionalization or alternatively the selective oxidation of secondary alcohols in the presence of primary alcohols occur. The scopes and limitations of the use of BrN3 are covered. eng
dc.language.iso eng
dc.publisher [Erscheinungsort nicht ermittelbar] : American Chemical Society
dc.relation.ispartofseries Journal of Organic Chemistry, The 88 (2023), Nr. 6
dc.rights CC BY 4.0 Unported
dc.rights.uri https://creativecommons.org/licenses/by/4.0
dc.subject Nitrogen compounds eng
dc.subject alcohol eng
dc.subject azide eng
dc.subject bromine derivative eng
dc.subject organic solvent eng
dc.subject.ddc 540 | Chemie
dc.subject.ddc 610 | Medizin, Gesundheit
dc.title Taming Bromine Azide for Use in Organic Solvents─Radical Bromoazidations and Alcohol Oxidations eng
dc.type Article
dc.type Text
dc.relation.essn 1520-6904
dc.relation.issn 0022-3263
dc.relation.doi https://doi.org/10.1021/acs.joc.2c03012
dc.bibliographicCitation.issue 6
dc.bibliographicCitation.volume 88
dc.bibliographicCitation.firstPage 3781
dc.bibliographicCitation.lastPage 3786
dc.description.version publishedVersion
tib.accessRights frei zug�nglich


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