Hybrid catalysis for enantioselective Baeyer-Villiger oxidation and stereoselective epoxidation: a Cp*Ir complex to fuel FMN and FAD reduction for flavoprotein monooxygenase modules

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Röllig, R.; Paul, C.E.; Rousselot-Pailley, P.; Kara, S.; Alphand, V.: Hybrid catalysis for enantioselective Baeyer-Villiger oxidation and stereoselective epoxidation: a Cp*Ir complex to fuel FMN and FAD reduction for flavoprotein monooxygenase modules. In: Reaction Chemistry & Engineering 12 (2023), S. 3117-3123. DOI: https://doi.org/10.1039/d3re00411b

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Abstract: 
Taking advantage of the unique properties of two-component flavo-monooxygenases and the ability of [Cp*Ir(bpy-OMe)H]+ to transfer hydrides to reduce flavins, we extended the scope of the pH- and oxygen-robust iridium(iii)-complex to drive the enzymatic reaction of a FMN-dependent Baeyer-Villiger monooxygenase and a FAD-dependent styrene monooxygenase (respectively FPMO Group C and E), using formic acid as H-donor for NADH recycling.
License of this version: CC BY-NC 3.0 Unported
Document Type: Article
Publishing status: publishedVersion
Issue Date: 2023
Appears in Collections:Naturwissenschaftliche Fakultät

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1 image of flag of Germany Germany 5 45.45%
2 image of flag of United States United States 4 36.36%
3 image of flag of No geo information available No geo information available 1 9.09%
4 image of flag of Ireland Ireland 1 9.09%
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