Design of amine-functionalized metal-organic frameworks for CO2 separation: the more amine, the better?

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dc.identifier.uri http://dx.doi.org/10.15488/797
dc.identifier.uri http://www.repo.uni-hannover.de/handle/123456789/821
dc.contributor.author Qiao, Zhiwei
dc.contributor.author Wang, Nanyi
dc.contributor.author Jiang, Jianwen
dc.contributor.author Zhou, Jian
dc.date.accessioned 2016-12-06T07:33:01Z
dc.date.available 2016-12-06T07:33:01Z
dc.date.issued 2016
dc.identifier.citation Qiao, Zhiwei; Wang, Nanyi; Jiang, Jianwen; Zhou, Jian: Design of amine-functionalized metal-organic frameworks for CO2 separation: the more amine, the better? In: Chemical communications 52 (2016), Nr. 5, S. 974-977. DOI: http://dx.doi.org/10.1039/C5CC07171B
dc.description.abstract A total of 41,825 metal-organic frameworks (MOFs) were computationally screened toward the design of amine-functionalized MOFs for CO2 separation. Both the optimal species and number of amine functional groups were examined for eight MOFs with good performance in terms of CO2 uptake and selectivity. It was revealed that more amine functional groups grafted on the MOFs do not lead to a better CO2 separation capability, and the concept of saturation degree of functional groups was proposed. The ethylene-diamine-functionalized MOF-74 membrane was predicted to possess high CO2 permeation separation capability, which was confirmed by the parallel experimental test of gas permeation. eng
dc.description.sponsorship National Key Basic Research Program of China/2013CB73350
dc.description.sponsorship National Natural Science Foundation of China/21376089
dc.description.sponsorship National Natural Science Foundation of China/91334202
dc.description.sponsorship China Postdoctoral Science Foundation/2014M560663
dc.description.sponsorship Guangdong Science Foundation/2014A03031200
dc.description.sponsorship Guangdong Science Foundation/2014A03031026
dc.description.sponsorship Fundamental Research Funds for the Central Universities/SCUT-2014ZB0012
dc.description.sponsorship Fundamental Research Funds for the Central Universities/2015ZP03
dc.description.sponsorship State Key Lab of Pulp and Paper Engineering Program/201444
dc.description.sponsorship National University of Singapore for CENGas
dc.language.iso eng
dc.publisher Cambridge : Royal Society of Chemistry
dc.relation.ispartofseries Chemical communications 52 (2016), Nr. 5
dc.rights Es gilt deutsches Urheberrecht. Das Dokument darf zum eigenen Gebrauch kostenfrei genutzt, aber nicht im Internet bereitgestellt oder an Außenstehende weitergegeben werden. Dieser Beitrag ist aufgrund einer (DFG-geförderten) Allianz- bzw. Nationallizenz frei zugänglich.
dc.subject metal-organic frameworks eng
dc.subject MOFs eng
dc.subject CO2 separation eng
dc.subject MOF-74 eng
dc.subject.ddc 540 | Chemie ger
dc.title Design of amine-functionalized metal-organic frameworks for CO2 separation: the more amine, the better? eng
dc.type article
dc.type Text
dc.relation.essn 1364-548X
dc.relation.issn 1359-7345
dc.relation.doi http://dx.doi.org/10.1039/C5CC07171B
dc.bibliographicCitation.issue 5
dc.bibliographicCitation.volume 52
dc.bibliographicCitation.firstPage 974
dc.bibliographicCitation.lastPage 977
dc.description.version publishedVersion
tib.accessRights frei zug�nglich


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