dc.identifier.uri |
http://dx.doi.org/10.15488/4933 |
|
dc.identifier.uri |
https://www.repo.uni-hannover.de/handle/123456789/4977 |
|
dc.contributor.author |
Jepsen, Julian
|
|
dc.contributor.author |
Milanese, Chiara
|
|
dc.contributor.author |
Puszkiel, Julian
|
|
dc.contributor.author |
Girella, Alessandro
|
|
dc.contributor.author |
Schiavo, Benedetto
|
|
dc.contributor.author |
Lozano, Gustavo A.
|
|
dc.contributor.author |
Capurso, Giovanni
|
|
dc.contributor.author |
von Colbe, Jose M. Bellosta
|
|
dc.contributor.author |
Marini, Amedeo
|
|
dc.contributor.author |
Kabelac, Stephan
|
|
dc.contributor.author |
Dornheim, Martin
|
|
dc.contributor.author |
Klassen, Thomas
|
|
dc.date.accessioned |
2019-06-03T11:46:23Z |
|
dc.date.available |
2019-06-03T11:46:23Z |
|
dc.date.issued |
2018 |
|
dc.identifier.citation |
Jepsen, J. et al: Fundamental Material Properties of the 2LiBH(4)-MgH2 Reactive Hydride Composite for Hydrogen Storage: (II) Kinetic Properties. In: Energies 11 (2018), Nr. 5, 1170. DOI: https://doi.org/10.3390/en11051170 |
|
dc.description.abstract |
Reaction kinetic behaviour and cycling stability of the 2LiBH(4)-MgH2 reactive hydride composite (Li-RHC) are experimentally determined and analysed as a basis for the design and development of hydrogen storage tanks. In addition to the determination and discussion about the properties; different measurement methods are applied and compared. The activation energies for both hydrogenation and dehydrogenation are determined by the Kissinger method and via the fitting of solid-state reaction kinetic models to isothermal volumetric measurements. Furthermore, the hydrogen absorption-desorption cycling stability is assessed by titration measurements. Finally, the kinetic behaviour and the reversible hydrogen storage capacity of the Li-RHC are discussed. |
eng |
dc.language.iso |
eng |
|
dc.publisher |
Basel : MDPI |
|
dc.relation.ispartofseries |
Energies 11 (2018), Nr. 5 |
|
dc.rights |
CC BY 4.0 Unported |
|
dc.rights.uri |
https://creativecommons.org/licenses/by/4.0/ |
|
dc.subject |
hydrogen storage |
eng |
dc.subject |
LiBH4/MgH2 |
eng |
dc.subject |
metal hydrides |
eng |
dc.subject |
borohydrides |
eng |
dc.subject |
reactive hydride composites |
eng |
dc.subject |
material properties |
eng |
dc.subject.ddc |
620 | Ingenieurwissenschaften und Maschinenbau
|
ger |
dc.title |
Fundamental Material Properties of the 2LiBH(4)-MgH2 Reactive Hydride Composite for Hydrogen Storage: (II) Kinetic Properties |
|
dc.type |
Article |
|
dc.type |
Text |
|
dc.relation.essn |
1996-1073 |
|
dc.relation.doi |
https://doi.org/10.3390/en11051170 |
|
dc.bibliographicCitation.issue |
5 |
|
dc.bibliographicCitation.volume |
11 |
|
dc.bibliographicCitation.firstPage |
1170 |
|
dc.description.version |
publishedVersion |
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tib.accessRights |
frei zug�nglich |
|