Fundamental Material Properties of the 2LiBH(4)-MgH2 Reactive Hydride Composite for Hydrogen Storage: (II) Kinetic Properties

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dc.identifier.uri http://dx.doi.org/10.15488/4933
dc.identifier.uri https://www.repo.uni-hannover.de/handle/123456789/4977
dc.contributor.author Jepsen, Julian
dc.contributor.author Milanese, Chiara
dc.contributor.author Puszkiel, Julian
dc.contributor.author Girella, Alessandro
dc.contributor.author Schiavo, Benedetto
dc.contributor.author Lozano, Gustavo A.
dc.contributor.author Capurso, Giovanni
dc.contributor.author von Colbe, Jose M. Bellosta
dc.contributor.author Marini, Amedeo
dc.contributor.author Kabelac, Stephan
dc.contributor.author Dornheim, Martin
dc.contributor.author Klassen, Thomas
dc.date.accessioned 2019-06-03T11:46:23Z
dc.date.available 2019-06-03T11:46:23Z
dc.date.issued 2018
dc.identifier.citation Jepsen, J. et al: Fundamental Material Properties of the 2LiBH(4)-MgH2 Reactive Hydride Composite for Hydrogen Storage: (II) Kinetic Properties. In: Energies 11 (2018), Nr. 5, 1170. DOI: https://doi.org/10.3390/en11051170
dc.description.abstract Reaction kinetic behaviour and cycling stability of the 2LiBH(4)-MgH2 reactive hydride composite (Li-RHC) are experimentally determined and analysed as a basis for the design and development of hydrogen storage tanks. In addition to the determination and discussion about the properties; different measurement methods are applied and compared. The activation energies for both hydrogenation and dehydrogenation are determined by the Kissinger method and via the fitting of solid-state reaction kinetic models to isothermal volumetric measurements. Furthermore, the hydrogen absorption-desorption cycling stability is assessed by titration measurements. Finally, the kinetic behaviour and the reversible hydrogen storage capacity of the Li-RHC are discussed. eng
dc.language.iso eng
dc.publisher Basel : MDPI
dc.relation.ispartofseries Energies 11 (2018), Nr. 5
dc.rights CC BY 4.0 Unported
dc.rights.uri https://creativecommons.org/licenses/by/4.0/
dc.subject hydrogen storage eng
dc.subject LiBH4/MgH2 eng
dc.subject metal hydrides eng
dc.subject borohydrides eng
dc.subject reactive hydride composites eng
dc.subject material properties eng
dc.subject.ddc 620 | Ingenieurwissenschaften und Maschinenbau ger
dc.title Fundamental Material Properties of the 2LiBH(4)-MgH2 Reactive Hydride Composite for Hydrogen Storage: (II) Kinetic Properties
dc.type article
dc.type Text
dc.relation.essn 1996-1073
dc.relation.doi https://doi.org/10.3390/en11051170
dc.bibliographicCitation.issue 5
dc.bibliographicCitation.volume 11
dc.bibliographicCitation.firstPage 1170
dc.description.version publishedVersion
tib.accessRights frei zug�nglich


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