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dc.identifier.uri http://dx.doi.org/10.15488/4117
dc.identifier.uri https://www.repo.uni-hannover.de/handle/123456789/4151
dc.contributor.author Sieland, Fabian ger
dc.contributor.author Schneider, Jenny ger
dc.contributor.author Bahnemann, Detlef W. ger
dc.date.accessioned 2018-12-06T14:12:48Z
dc.date.available 2018-12-06T14:12:48Z
dc.date.issued 2017
dc.identifier.citation Sieland, F.; Schneider, J.; Bahnemann, D.W.: Fractal Charge Carrier Kinetics in TiO2. In: Journal of Physical Chemistry C 121 (2017), S. 24282-24291. DOI: https://doi.org/10.1021/acs.jpcc.7b07087 ger
dc.description.abstract Charge carrier recombination kinetics of TiO2 powder samples were analyzed in the time domain ranging from 50 ns to 1 ms. The transient reflectance signals of the charge carriers observed by laser flash photolysis spectroscopy do not fit to simple second order kinetics as expected for the recombination of trapped electrons and holes. The deviation from second order reaction dynamics could rather be explained by the segregation of charge carriers and the fractal dimension of the semiconductor agglomerates. According to the fractal reaction kinetics, the time dependent rate coefficient kf (kf = k2,ft–h) has been employed instead of the second order rate constant k2, where the fractal parameter h describes the dimension of the system. This model could successfully be used to describe charge carrier signals in all observed time domains. Moreover, the model was compared with the concept developed by Shuttle et al., which proposes that the charge carrier signals decay following a power-law. The benefits of the fractal model proposed here include the possibility to describe and analyze influences of the morphology on the fractal parameter h and its applicability over a broad range of time domains and excitation energies. ger
dc.language.iso eng ger
dc.publisher Washington D.C. : American Chemical Society
dc.relation.ispartofseries Journal of Physical Chemistry C 121 (2017) ger
dc.rights ACS AuthorChoice License ger
dc.rights.uri https://pubs.acs.org/page/policy/authorchoice_termsofuse.html
dc.subject charge carriers eng
dc.subject laser flash photolysis spectroscopy eng
dc.subject kinetics eng
dc.subject.ddc 540 | Chemie ger
dc.title Fractal Charge Carrier Kinetics in TiO2 ger
dc.type article ger
dc.type Text ger
dc.relation.doi 10.1021/acs.jpcc.7b07087
dc.description.version publishedVersion ger


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