dc.identifier.uri | http://dx.doi.org/10.15488/2466 | |
dc.identifier.uri | http://www.repo.uni-hannover.de/handle/123456789/2492 | |
dc.contributor.author | Berthold, Hans Joachim | |
dc.contributor.author | Ludwig, Wolfgang | |
dc.date.accessioned | 2017-11-24T11:46:32Z | |
dc.date.available | 2017-11-24T11:46:32Z | |
dc.date.issued | 1980 | |
dc.identifier.citation | Berthold, H.J.; Ludwig, W.: Präparative und röntgenographische Untersuchungen über Cäsium-Silber-Gold(III)-Chlorid. In: Zeitschrift für Naturforschung - Section B Journal of Chemical Sciences 35 (1980), Nr. 6, S. 651-656. DOI: https://doi.org/10.1515/znb-1980-0601 | |
dc.description.abstract | Cesium silver gold(III) chloride has been prepared from hydrochloric acid solutions. The composition of the preparations is variable and depends on the ratio [Au(III)]/[Ag(I)] in solution. It corresponds to the formula Cs2Ag1-xAu1+x/3Cl6. In the range 0 ≤ x ≤ 0,64 six crystallographically different phases have been observed. Above x = 0,42 a cubic phase is obtained. The stoichiometric compound Cs2AgAuCl6 is obtained only from solutions with [Au(III)]/[Ag(I)] < 1. Reports in the literature which claim the stoichiometric compound Cs2AgAuCl6 to exist in a cubic and in a tetragonal form cannot be confirmed. Cs2AgAuCl6 crystallizes orthorhombically with the lattice constants a = 15,21 Å, b = 15,16 Å and c = 10,32 Å (Z = 8). | eng |
dc.language.iso | ger | |
dc.publisher | Berlin : De Gruyter | |
dc.relation.ispartofseries | Zeitschrift für Naturforschung - Section B Journal of Chemical Sciences 35 (1980), Nr. 6 | |
dc.rights | CC BY-NC-ND 3.0 Unported | |
dc.rights.uri | https://creativecommons.org/licenses/by-nc-nd/3.0/ | |
dc.subject | Cesium Silver Gold(III) Chloride | eng |
dc.subject | Chemical Composition | eng |
dc.subject | Lattice Constants | eng |
dc.subject | Nonstoichiometric Phases | eng |
dc.subject | Preparation | eng |
dc.subject.ddc | 540 | Chemie | ger |
dc.title | Präparative und röntgenographische Untersuchungen über Cäsium-Silber-Gold(III)-Chlorid | ger |
dc.type | Article | |
dc.type | Text | |
dc.relation.essn | 1865-7117 | |
dc.relation.issn | 0932-0776 | |
dc.relation.doi | https://doi.org/10.1515/znb-1980-0601 | |
dc.bibliographicCitation.issue | 6 | |
dc.bibliographicCitation.volume | 35 | |
dc.bibliographicCitation.firstPage | 651 | |
dc.bibliographicCitation.lastPage | 656 | |
dc.description.version | publishedVersion | |
tib.accessRights | frei zug�nglich |
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