Präparative und röntgenographische Untersuchungen über Cäsium-Silber-Gold(III)-Chlorid

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dc.identifier.uri http://dx.doi.org/10.15488/2466
dc.identifier.uri http://www.repo.uni-hannover.de/handle/123456789/2492
dc.contributor.author Berthold, Hans Joachim
dc.contributor.author Ludwig, Wolfgang
dc.date.accessioned 2017-11-24T11:46:32Z
dc.date.available 2017-11-24T11:46:32Z
dc.date.issued 1980
dc.identifier.citation Berthold, H.J.; Ludwig, W.: Präparative und röntgenographische Untersuchungen über Cäsium-Silber-Gold(III)-Chlorid. In: Zeitschrift für Naturforschung - Section B Journal of Chemical Sciences 35 (1980), Nr. 6, S. 651-656. DOI: https://doi.org/10.1515/znb-1980-0601
dc.description.abstract Cesium silver gold(III) chloride has been prepared from hydrochloric acid solutions. The composition of the preparations is variable and depends on the ratio [Au(III)]/[Ag(I)] in solution. It corresponds to the formula Cs2Ag1-xAu1+x/3Cl6. In the range 0 ≤ x ≤ 0,64 six crystallographically different phases have been observed. Above x = 0,42 a cubic phase is obtained. The stoichiometric compound Cs2AgAuCl6 is obtained only from solutions with [Au(III)]/[Ag(I)] < 1. Reports in the literature which claim the stoichiometric compound Cs2AgAuCl6 to exist in a cubic and in a tetragonal form cannot be confirmed. Cs2AgAuCl6 crystallizes orthorhombically with the lattice constants a = 15,21 Å, b = 15,16 Å and c = 10,32 Å (Z = 8). eng
dc.language.iso ger
dc.publisher Berlin : De Gruyter
dc.relation.ispartofseries Zeitschrift für Naturforschung - Section B Journal of Chemical Sciences 35 (1980), Nr. 6
dc.rights CC BY-NC-ND 3.0 Unported
dc.rights.uri https://creativecommons.org/licenses/by-nc-nd/3.0/
dc.subject Cesium Silver Gold(III) Chloride eng
dc.subject Chemical Composition eng
dc.subject Lattice Constants eng
dc.subject Nonstoichiometric Phases eng
dc.subject Preparation eng
dc.subject.ddc 540 | Chemie ger
dc.title Präparative und röntgenographische Untersuchungen über Cäsium-Silber-Gold(III)-Chlorid ger
dc.type article
dc.type Text
dc.relation.essn 1865-7117
dc.relation.issn 0932-0776
dc.relation.doi https://doi.org/10.1515/znb-1980-0601
dc.bibliographicCitation.issue 6
dc.bibliographicCitation.volume 35
dc.bibliographicCitation.firstPage 651
dc.bibliographicCitation.lastPage 656
dc.description.version publishedVersion
tib.accessRights frei zug�nglich


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