Impulsphotolytische Untersuchungen zum Mechanismus der photochemischen WOLFF-Umlagerung

Bölsing, Friedrich; Spanuth. E.

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dc.identifier.uri	http://dx.doi.org/10.15488/2428
dc.identifier.uri	http://www.repo.uni-hannover.de/handle/123456789/2454
dc.contributor.author	Bölsing, Friedrich
dc.contributor.author	Spanuth. E.
dc.date.accessioned	2017-11-24T10:31:39Z
dc.date.available	2017-11-24T10:31:39Z
dc.date.issued	1976
dc.identifier.citation	Bölsing, F.; Spanuth, E.: Impulsphotolytische Untersuchungen zum Mechanismus der photochemischen WOLFF-Umlagerung. In: Zeitschrift für Naturforschung - Section B Journal of Chemical Sciences 31 (1976), Nr. 10, S. 1391-1396. DOI: https://doi.org/10.1515/znb-1976-1021
dc.description.abstract	9,10-Diazophenanthrone undergoes WOLFF rearrangement in alcoholic solvents and yields esters of 9-fluorene carboxylic acid. By flash light photolysis four intermediates could be detected. Kinetic measurements showed that the ketene formed by photolysis reacts with the solvent to give a cyclopentadienylic carbanion, which is protonated. A carbene or an oxirene intermediate could not be found.	eng
dc.language.iso	ger
dc.publisher	Berlin : De Gruyter
dc.relation.ispartofseries	Zeitschrift für Naturforschung - Section B Journal of Chemical Sciences 31 (1976), Nr. 10
dc.rights	CC BY-NC-ND 3.0 Unported
dc.rights.uri	https://creativecommons.org/licenses/by-nc-nd/3.0/
dc.subject	9, 10-Diazophenantlirone	eng
dc.subject	Diphenylene Ketene	eng
dc.subject	Flash Light Photolysis	eng
dc.subject	Kinetic Measurements	eng
dc.subject	WOLFF Rearrangement	eng
dc.subject.ddc	540 \| Chemie	ger
dc.title	Impulsphotolytische Untersuchungen zum Mechanismus der photochemischen WOLFF-Umlagerung	ger
dc.type	Article
dc.type	Text
dc.relation.essn	1865-7117
dc.relation.issn	0932-0776
dc.relation.doi	https://doi.org/10.1515/znb-1976-1021
dc.bibliographicCitation.issue	10
dc.bibliographicCitation.volume	31
dc.bibliographicCitation.firstPage	1391
dc.bibliographicCitation.lastPage	1396
dc.description.version	publishedVersion
tib.accessRights	frei zug�nglich