Impulsphotolytische Untersuchungen zum Mechanismus der photochemischen WOLFF-Umlagerung

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dc.identifier.uri http://dx.doi.org/10.15488/2428
dc.identifier.uri http://www.repo.uni-hannover.de/handle/123456789/2454
dc.contributor.author Bölsing, Friedrich
dc.contributor.author Spanuth. E.
dc.date.accessioned 2017-11-24T10:31:39Z
dc.date.available 2017-11-24T10:31:39Z
dc.date.issued 1976
dc.identifier.citation Bölsing, F.; Spanuth, E.: Impulsphotolytische Untersuchungen zum Mechanismus der photochemischen WOLFF-Umlagerung. In: Zeitschrift für Naturforschung - Section B Journal of Chemical Sciences 31 (1976), Nr. 10, S. 1391-1396. DOI: https://doi.org/10.1515/znb-1976-1021
dc.description.abstract 9,10-Diazophenanthrone undergoes WOLFF rearrangement in alcoholic solvents and yields esters of 9-fluorene carboxylic acid. By flash light photolysis four intermediates could be detected. Kinetic measurements showed that the ketene formed by photolysis reacts with the solvent to give a cyclopentadienylic carbanion, which is protonated. A carbene or an oxirene intermediate could not be found. eng
dc.language.iso ger
dc.publisher Berlin : De Gruyter
dc.relation.ispartofseries Zeitschrift für Naturforschung - Section B Journal of Chemical Sciences 31 (1976), Nr. 10
dc.rights CC BY-NC-ND 3.0 Unported
dc.rights.uri https://creativecommons.org/licenses/by-nc-nd/3.0/
dc.subject 9, 10-Diazophenantlirone eng
dc.subject Diphenylene Ketene eng
dc.subject Flash Light Photolysis eng
dc.subject Kinetic Measurements eng
dc.subject WOLFF Rearrangement eng
dc.subject.ddc 540 | Chemie ger
dc.title Impulsphotolytische Untersuchungen zum Mechanismus der photochemischen WOLFF-Umlagerung ger
dc.type article
dc.type Text
dc.relation.essn 1865-7117
dc.relation.issn 0932-0776
dc.relation.doi https://doi.org/10.1515/znb-1976-1021
dc.bibliographicCitation.issue 10
dc.bibliographicCitation.volume 31
dc.bibliographicCitation.firstPage 1391
dc.bibliographicCitation.lastPage 1396
dc.description.version publishedVersion
tib.accessRights frei zug�nglich


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