Dimere und Ketten in Praseodym(III)acetat-sesquihydrat, Pr(CH3COO)3l, 5H20

Show simple item record

dc.identifier.uri http://dx.doi.org/10.15488/2414
dc.identifier.uri http://www.repo.uni-hannover.de/handle/123456789/2440
dc.contributor.author Lossin, Adalbert
dc.contributor.author Meyer, Gerd
dc.date.accessioned 2017-11-24T10:07:37Z
dc.date.available 2017-11-24T10:07:37Z
dc.date.issued 1992
dc.identifier.citation Lossin, A.; Meyer, G.: Dimere und Ketten in Praseodym(III)acetat-sesquihydrat, Pr(CH3COO)3l, 5H20. In: Zeitschrift für Naturforschung - Section B Journal of Chemical Sciences 47 (1992), Nr. 11, S. 1602-1608. DOI: https://doi.org/10.1515/znb-1992-1114
dc.description.abstract Pr(CH3COO)3· 1.5 H2O crystallizes with the triclinic system, P̄1̄ (no. 2), Z = 4, a = 844.2(4), b = 1009.8(5), c = 1340.1(7) pm, α = 87.10(5), β = 76.25(6), y = 75.65(2)°, Vm = 161.9(1) cm3/mol, R = 0.049, Rw = 0.035. The crystal structure contains centrosymmetric dimers {[Pr(CH3COO)4(H2O)]-}2 and one-dimensional chains ∞1[Pr(CH3COO)2(H2O)]+ along the [100] direction. Both units are built up by bridging acetate groups. The chains are linked by the dimers to layers parallel (101) sharing oxygen atoms. Crystal water molecules between these planes form hydrogen bonds to neighbouring layers. eng
dc.language.iso ger
dc.publisher Berlin : De Gruyter
dc.relation.ispartofseries Zeitschrift für Naturforschung - Section B Journal of Chemical Sciences 47 (1992), Nr. 11
dc.rights CC BY-NC-ND 3.0
dc.rights.uri https://creativecommons.org/licenses/by-nc-nd/3.0/
dc.subject Crystal Structure eng
dc.subject Praseodymium Acetate eng
dc.subject Sesquihydrate eng
dc.subject Synthesis eng
dc.subject Thermal Behaviour eng
dc.subject.ddc 540 | Chemie ger
dc.title Dimere und Ketten in Praseodym(III)acetat-sesquihydrat, Pr(CH3COO)3l, 5H20
dc.type article
dc.type Text
dc.relation.essn 1865-7117
dc.relation.issn 0932-0776
dc.relation.doi https://doi.org/10.1515/znb-1992-1114
dc.bibliographicCitation.issue 11
dc.bibliographicCitation.volume 47
dc.bibliographicCitation.firstPage 1602
dc.bibliographicCitation.lastPage 1608
dc.description.version publishedVersion
tib.accessRights frei zug�nglich


Files in this item

The following license files are associated with this item:

This item appears in the following Collection(s):

Show simple item record

 

Search the repository


Browse

My Account

Usage Statistics