dc.identifier.uri | http://dx.doi.org/10.15488/2411 | |
dc.identifier.uri | http://www.repo.uni-hannover.de/handle/123456789/2437 | |
dc.contributor.author | Schatte, G. | |
dc.contributor.author | Willner, H. | |
dc.date.accessioned | 2017-11-24T09:37:04Z | |
dc.date.available | 2017-11-24T09:37:04Z | |
dc.date.issued | 1991 | |
dc.identifier.citation | Schatte, G.; Willner, H.: Die Wechselwirkung von N3F mit Lewis-Säuren und HF. N3F als möglicher Vorläufer für die Synthese von N3+-Salzen. In: Zeitschrift für Naturforschung - Section B Journal of Chemical Sciences 46 (1991), Nr. 4, S. 483-489. DOI: https://doi.org/10.1515/znb-1991-0410 | |
dc.description.abstract | Triazadienyl fluoride, N3F, forms stable adducts with BF3 and AsF5 at low temperatures, as demonstrated by infrared measurements. The Lewis acids are bonded to the Nα-atom of N3F, as deduced from the data for 15N-isotopically enriched N3F. The basicity of N3F is comparable to that of ethine and ethene, according to the HF stretching frequency of the N3F/HF complex isolated in an argon matrix. Despite the low NF bond energy (< 150 kJ/mol), abstraction of the fluoride ion and formation of an N3+ salt was not possible. The different behavior of N3F and ClN3 towards Lewis acids is discussed. | eng |
dc.language.iso | ger | |
dc.publisher | Berlin : De Gruyter | |
dc.relation.ispartofseries | Zeitschrift für Naturforschung - Section B Journal of Chemical Sciences 46 (1991), Nr. 4 | |
dc.rights | CC BY-NC-ND 3.0 Unported | |
dc.rights.uri | https://creativecommons.org/licenses/by-nc-nd/3.0/ | |
dc.subject | Triazadienyl fluoride | eng |
dc.subject | N3F | eng |
dc.subject | Lewis acids | eng |
dc.subject | N3+Salts | eng |
dc.subject.ddc | 540 | Chemie | ger |
dc.title | Die Wechselwirkung von N3F mit Lewis-Säuren und HF. N3F als möglicher Vorläufer für die Synthese von N3+-Salzen | ger |
dc.type | Article | |
dc.type | Text | |
dc.relation.essn | 1865-7117 | |
dc.relation.issn | 0932-0776 | |
dc.relation.doi | https://doi.org/10.1515/znb-1991-0410 | |
dc.bibliographicCitation.issue | 4 | |
dc.bibliographicCitation.volume | 46 | |
dc.bibliographicCitation.firstPage | 483 | |
dc.bibliographicCitation.lastPage | 489 | |
dc.description.version | publishedVersion | |
tib.accessRights | frei zug�nglich |
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