dc.identifier.uri | http://dx.doi.org/10.15488/2396 | |
dc.identifier.uri | http://www.repo.uni-hannover.de/handle/123456789/2422 | |
dc.contributor.author | Rühl, Wolfgang | |
dc.contributor.author | Bölsing, Friedrich | |
dc.contributor.author | Hofer, Edgar | |
dc.contributor.author | Speer, Dietrich | |
dc.contributor.author | Jansen, Martin | |
dc.date.accessioned | 2017-11-24T08:14:43Z | |
dc.date.available | 2017-11-24T08:14:43Z | |
dc.date.issued | 1986 | |
dc.identifier.citation | Rühl, W.; Bölsing, F.; Hofer, E.; Speer, D.; Jansen, M.: Das Ketocarben-Oxiren-Gleichgewicht unter einem präparativen Aspekt≠. In: Zeitschrift für Naturforschung - Section B Journal of Chemical Sciences 41 (1986), Nr. 6, S. 772-775. DOI: https://doi.org/10.1515/znb-1986-0616 | |
dc.description.abstract | The photochemical decomposition of α-diazoketone 1 in toluene gives rise to the formation of the well known keto carbene-oxirene equilibrium from which not only the product of the Wolff rearrangem ent can be derived but also the com pounds 5, 6 and 7 which are formed directly via the corresponding keto carbenes A and B respectively. Formation of the azulene 6 is unexpected in this context, it's structure could be revealed by X-ray analysis. The results may be regarded as an additional contribution to the mechanism of the Wolff rearrangement, but what is more, they could serve as a model for the feasibility of mechanistic oxirene chemistry in a more preparative aspect. | eng |
dc.language.iso | ger | |
dc.publisher | Berlin : De Gruyter | |
dc.relation.ispartofseries | Zeitschrift für Naturforschung - Section B Journal of Chemical Sciences 41 (1986), Nr. 6 | |
dc.rights | CC BY-NC-ND 3.0 Unported | |
dc.rights.uri | https://creativecommons.org/licenses/by-nc-nd/3.0/ | |
dc.subject | Azulenes | eng |
dc.subject | Oxirenes | eng |
dc.subject | Oxo Carbenes | eng |
dc.subject | Wolff Rearrangement | eng |
dc.subject.ddc | 540 | Chemie | ger |
dc.title | Das Ketocarben-Oxiren-Gleichgewicht unter einem präparativen Aspekt≠ | ger |
dc.type | Article | |
dc.type | Text | |
dc.relation.essn | 1865-7117 | |
dc.relation.issn | 0932-0776 | |
dc.relation.doi | https://doi.org/10.1515/znb-1986-0616 | |
dc.bibliographicCitation.issue | 6 | |
dc.bibliographicCitation.volume | 41 | |
dc.bibliographicCitation.firstPage | 772 | |
dc.bibliographicCitation.lastPage | 775 | |
dc.description.version | publishedVersion | |
tib.accessRights | frei zug�nglich |
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