Darstellung und Kristallstruktur von Bis-(N-Methymydroxylamido(1-)-O.N)(N-methyl-N-oxo-dithiocarbamato-O.S)-oxo-molybdän(VI)

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dc.identifier.uri http://dx.doi.org/10.15488/2392
dc.identifier.uri http://www.repo.uni-hannover.de/handle/123456789/2418
dc.contributor.author Holzbach, Wolfgang
dc.contributor.author Wieghardt, Karl
dc.contributor.author Weiss, Johannes
dc.date.accessioned 2017-11-24T08:14:41Z
dc.date.available 2017-11-24T08:14:41Z
dc.date.issued 1981
dc.identifier.citation Holzbach, W.; Wieghardt, K.; Weiss, J.: Darstellung und Kristallstruktur von Bis-(N-Methymydroxylamido(1-)-O.N)(N-methyl-N-oxo-dithiocarbamato-O.S)-oxo-molybdän(VI). In: Zeitschrift für Naturforschung - Section B Journal of Chemical Sciences 36 (1981), Nr. 3, S. 289-292. DOI: https://doi.org/10.1515/znb-1981-0302
dc.description.abstract The reaction of [MoO2((CH3)HN-O)2] and N-methylhydroxylammoniumchloride in an aqueous suspension with CS2 yields red crystals of the analytical composition MOC4H14N3O4S2. The crystal structure has been determined by single crystal X-ray diffraction analysis. The compound crystallizes in the monoclinic space group P21/c, with cell constants a= 1333.2(3), b = 814.2(2), c = 2179.8(6) pm, β = 105.42(2)°, and Z = 8. The final R-value is 4.5% for 2965 unique reflexions. The structure consists of two crystallographically independent neutral complexes of molybdenum(VI). The geometry about the molybdenum is a distorted pentagonal bipyramid containing a terminal oxygen atom, two N-methylhydroxylamido(1-) ligands coordinated via the O-and N-atoms and an N-methyl-N-oxo-dithiocarbamato(2-) ligand forming a planar five membered ring with the molybdenum(VI) center (O,S-coordination). eng
dc.language.iso ger
dc.publisher Berlin : De Gruyter
dc.relation.ispartofseries Zeitschrift für Naturforschung - Section B Journal of Chemical Sciences 36 (1981), Nr. 3
dc.rights CC BY-NC-ND 3.0
dc.rights.uri https://creativecommons.org/licenses/by-nc-nd/3.0/
dc.subject Bis(N-methylhydroxylamido(1-)-O, N)(N-methyl-N-oxo-dithiocarbamato-O,S)-oxo-molybdenum(VI) eng
dc.subject Crystal Structure eng
dc.subject Synthesis eng
dc.subject.ddc 540 | Chemie ger
dc.title Darstellung und Kristallstruktur von Bis-(N-Methymydroxylamido(1-)-O.N)(N-methyl-N-oxo-dithiocarbamato-O.S)-oxo-molybdän(VI)
dc.type article
dc.type Text
dc.relation.essn 1865-7117
dc.relation.issn 0932-0776
dc.relation.doi https://doi.org/10.1515/znb-1981-0302
dc.bibliographicCitation.issue 3
dc.bibliographicCitation.volume 36
dc.bibliographicCitation.firstPage 289
dc.bibliographicCitation.lastPage 292
dc.description.version publishedVersion
tib.accessRights frei zug�nglich


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