dc.identifier.uri | http://dx.doi.org/10.15488/2369 | |
dc.identifier.uri | http://www.repo.uni-hannover.de/handle/123456789/2395 | |
dc.contributor.author | Steffen, Frank | |
dc.contributor.author | Meyer, Gerd | |
dc.date.accessioned | 2017-11-24T07:40:25Z | |
dc.date.available | 2017-11-24T07:40:25Z | |
dc.date.issued | 1995 | |
dc.identifier.citation | Steffen, F.; Meyer, G.: [Er14(C2)2(N)2]I24 - ein Iodid mit einem oligomeren, heterointerstitiellen Cluster. In: Zeitschrift für Naturforschung - Section B Journal of Chemical Sciences 50 (1995), Nr. 10, S. 1570-1573. DOI: https://doi.org/10.1515/znb-1995-1024 | |
dc.description.abstract | [Er14(C2)2(N)2]l24 (triclinic, P1̅, a = 966.3(4) pm. b = 1027.6(2) pm. c = 1663.4(4) pm, α = 101.374(9)°, β = 92.853(14)°, γ = 112.83(2)°, Z = 2) is obtained as red-brown single crystals through a conproportionation reaction of Erl3 and erbium in the presence of carbon and NaN3 in a sealed niobium container. It contains discrete, tetrameric [Er14(C2)2(N)2] clusters that are built from two octahedra and two tetrahedra connected via common edges. The octahedral voids are filled with C2 units and the tetrahedral voids with N atoms. Each discrete [Er14(C2)2(N)2] cluster is surrounded by 32 iodide ligands which connect six clusters via i-a and a-a bridges. | eng |
dc.language.iso | ger | |
dc.publisher | Berlin : De Gruyter | |
dc.relation.ispartofseries | Zeitschrift für Naturforschung - Section B Journal of Chemical Sciences 50 (1995), Nr. 10 | |
dc.rights | CC BY-NC-ND 3.0 Unported | |
dc.rights.uri | https://creativecommons.org/licenses/by-nc-nd/3.0/ | |
dc.subject | Cluster | eng |
dc.subject | Crystal Structure | eng |
dc.subject | Erbium Iodide Dicarbide Nitride | eng |
dc.subject | Halides | eng |
dc.subject | Rare Earth Elements | eng |
dc.subject.ddc | 540 | Chemie | ger |
dc.title | [Er14(C2)2(N)2]I24 - ein Iodid mit einem oligomeren, heterointerstitiellen Cluster | eng |
dc.type | Article | |
dc.type | Text | |
dc.relation.essn | 1865-7117 | |
dc.relation.issn | 0932-0776 | |
dc.relation.doi | https://doi.org/10.1515/znb-1995-1024 | |
dc.bibliographicCitation.issue | 10 | |
dc.bibliographicCitation.volume | 50 | |
dc.bibliographicCitation.firstPage | 1570 | |
dc.bibliographicCitation.lastPage | 1573 | |
dc.description.version | publishedVersion | |
tib.accessRights | frei zug�nglich |
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