[Er14(C2)2(N)2]I24 - ein Iodid mit einem oligomeren, heterointerstitiellen Cluster

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dc.identifier.uri http://dx.doi.org/10.15488/2369
dc.identifier.uri http://www.repo.uni-hannover.de/handle/123456789/2395
dc.contributor.author Steffen, Frank
dc.contributor.author Meyer, Gerd
dc.date.accessioned 2017-11-24T07:40:25Z
dc.date.available 2017-11-24T07:40:25Z
dc.date.issued 1995
dc.identifier.citation Steffen, F.; Meyer, G.: [Er14(C2)2(N)2]I24 - ein Iodid mit einem oligomeren, heterointerstitiellen Cluster. In: Zeitschrift für Naturforschung - Section B Journal of Chemical Sciences 50 (1995), Nr. 10, S. 1570-1573. DOI: https://doi.org/10.1515/znb-1995-1024
dc.description.abstract [Er14(C2)2(N)2]l24 (triclinic, P1̅, a = 966.3(4) pm. b = 1027.6(2) pm. c = 1663.4(4) pm, α = 101.374(9)°, β = 92.853(14)°, γ = 112.83(2)°, Z = 2) is obtained as red-brown single crystals through a conproportionation reaction of Erl3 and erbium in the presence of carbon and NaN3 in a sealed niobium container. It contains discrete, tetrameric [Er14(C2)2(N)2] clusters that are built from two octahedra and two tetrahedra connected via common edges. The octahedral voids are filled with C2 units and the tetrahedral voids with N atoms. Each discrete [Er14(C2)2(N)2] cluster is surrounded by 32 iodide ligands which connect six clusters via i-a and a-a bridges. eng
dc.language.iso ger
dc.publisher Berlin : De Gruyter
dc.relation.ispartofseries Zeitschrift für Naturforschung - Section B Journal of Chemical Sciences 50 (1995), Nr. 10
dc.rights CC BY-NC-ND 3.0
dc.rights.uri https://creativecommons.org/licenses/by-nc-nd/3.0/
dc.subject Cluster eng
dc.subject Crystal Structure eng
dc.subject Erbium Iodide Dicarbide Nitride eng
dc.subject Halides eng
dc.subject Rare Earth Elements eng
dc.subject.ddc 540 | Chemie ger
dc.title [Er14(C2)2(N)2]I24 - ein Iodid mit einem oligomeren, heterointerstitiellen Cluster
dc.type article
dc.type Text
dc.relation.essn 1865-7117
dc.relation.issn 0932-0776
dc.relation.doi https://doi.org/10.1515/znb-1995-1024
dc.bibliographicCitation.issue 10
dc.bibliographicCitation.volume 50
dc.bibliographicCitation.firstPage 1570
dc.bibliographicCitation.lastPage 1573
dc.description.version publishedVersion
tib.accessRights frei zug�nglich


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