A rectangular Ni-Fe cluster with unusual cyanide bridges

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dc.identifier.uri http://dx.doi.org/10.15488/2156
dc.identifier.uri http://www.repo.uni-hannover.de/handle/123456789/2181
dc.contributor.author Krüger, Christoph
dc.contributor.author Sato, Hiroki
dc.contributor.author Matsumoto, Takuto
dc.contributor.author Shiga, Takuya
dc.contributor.author Newton, Graham N.
dc.contributor.author Renz, Franz
dc.contributor.author Oshio, Hiroki
dc.date.accessioned 2017-10-30T13:12:53Z
dc.date.available 2017-10-30T13:12:53Z
dc.date.issued 2012
dc.identifier.citation Krüger, C.; Sato, H.; Matsumoto, T.; Shiga, T.; Newton, G.N. et al.: A rectangular Ni-Fe cluster with unusual cyanide bridges. In: Dalton Transactions 41 (2012), Nr. 37, S. 11270-11272. DOI: https://doi.org/10.1039/c2dt31152f
dc.description.abstract An asymmetric polycyanide iron complex, K2[Fe III(L1)(CN)4](MeOH) (HL1 = 2,2′-(1H-pyrazole-3,5- diyl)bis-pyridine), was synthesized and its complexation compatibility with nickel ions was examined. Two kinds of enantiomeric nickel-iron squares were obtained in the presence of a chiral bidentate capping ligand. The compounds display unusual cyanide bridge geometry and have ferromagnetic interactions between nickel and iron ions. © 2013 The Royal Society of Chemistry. eng
dc.language.iso eng
dc.publisher Cambridge : Royal Society of Chemistry
dc.relation.ispartofseries Dalton Transactions 41 (2012), Nr. 37
dc.rights Es gilt deutsches Urheberrecht. Das Dokument darf zum eigenen Gebrauch kostenfrei genutzt, aber nicht im Internet bereitgestellt oder an Außenstehende weitergegeben werden. Dieser Beitrag ist aufgrund einer (DFG-geförderten) Allianz- bzw. Nationallizenz frei zugänglich.
dc.subject Capping ligands eng
dc.subject Cyanide bridge eng
dc.subject Ferro-magnetic interactions eng
dc.subject Iron complex eng
dc.subject Iron ions eng
dc.subject Nickel ions eng
dc.subject Nickel irons eng
dc.subject Cyanides eng
dc.subject Metal ions eng
dc.subject Nickel eng
dc.subject Synthesis (chemical) eng
dc.subject Iron compounds eng
dc.subject.ddc 540 | Chemie ger
dc.title A rectangular Ni-Fe cluster with unusual cyanide bridges eng
dc.type article
dc.type Text
dc.relation.issn 1477-9226
dc.relation.doi https://doi.org/10.1039/c2dt31152f
dc.bibliographicCitation.issue 37
dc.bibliographicCitation.volume 41
dc.bibliographicCitation.firstPage 11270
dc.bibliographicCitation.lastPage 11272
dc.description.version publishedVersion
tib.accessRights frei zug�nglich

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