dc.identifier.uri |
http://dx.doi.org/10.15488/1964 |
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dc.identifier.uri |
http://www.repo.uni-hannover.de/handle/123456789/1989 |
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dc.contributor.author |
Dreissigacker, Ingo
|
|
dc.contributor.author |
Lein, Manfred
|
|
dc.date.accessioned |
2017-09-22T14:17:43Z |
|
dc.date.available |
2017-09-22T14:17:43Z |
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dc.date.issued |
2014 |
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dc.identifier.citation |
Dreissigacker, I.; Lein, M.: Photoelectron circular dichroism of chiral molecules studied with a continuum-state-corrected strong-field approximation. In: Physical Review A - Atomic, Molecular, and Optical Physics 89 (2014), Nr. 5, 53406. DOI: https://doi.org/10.1103/PhysRevA.89.053406 |
|
dc.description.abstract |
Motivated by recent experiments on circular dichroism in the photoelectron momentum distributions from strong-field ionization of chiral molecules [C. Lux, Angew. Chem. Int. Ed. 51, 5001 (2012)1433-785110.1002/anie.201109035; C. S. Lehmann, J. Chem. Phys. 139, 234307 (2013)JCPSA60021-960610.1063/1.4844295], we investigate the origin of this effect theoretically. We show that it is not possible to describe photoelectron circular dichroism with the commonly used strong-field approximation due to its plane-wave nature. We therefore apply the Born approximation to the scattering state and use this as a continuum-state correction in the strong-field approximation. We obtain electron distributions for the molecules camphor and fenchone. In order to gain physical insight into the process, we study the contributions of individual molecular orientations. © 2014 American Physical Society. |
eng |
dc.description.sponsorship |
DFG/EXC/QUEST |
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dc.language.iso |
eng |
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dc.publisher |
College Park, MD : American Physical Society |
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dc.relation.ispartofseries |
Physical Review A 89 (2014), Nr. 5 |
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dc.rights |
Es gilt deutsches Urheberrecht. Das Dokument darf zum eigenen Gebrauch kostenfrei genutzt, aber nicht im Internet bereitgestellt oder an Außenstehende weitergegeben werden. |
|
dc.subject |
Dichroism |
eng |
dc.subject |
Molecules |
eng |
dc.subject |
Photoelectrons |
eng |
dc.subject |
Photoionization |
eng |
dc.subject |
Photons |
eng |
dc.subject |
Chiral molecule |
eng |
dc.subject |
Electron distributions |
eng |
dc.subject |
Fenchone |
eng |
dc.subject |
Momentum distributions |
eng |
dc.subject |
Plane wave |
eng |
dc.subject |
Scattering state |
eng |
dc.subject |
Strong field ionization |
eng |
dc.subject |
Strong-field approximations |
eng |
dc.subject |
Stereochemistry |
eng |
dc.subject.ddc |
530 | Physik
|
ger |
dc.title |
Photoelectron circular dichroism of chiral molecules studied with a continuum-state-corrected strong-field approximation |
|
dc.type |
Article |
|
dc.type |
Text |
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dc.relation.issn |
10502947 |
|
dc.relation.doi |
https://doi.org/10.1103/PhysRevA.89.053406 |
|
dc.bibliographicCitation.issue |
5 |
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dc.bibliographicCitation.volume |
89 |
|
dc.bibliographicCitation.firstPage |
53406 |
|
dc.description.version |
publishedVersion |
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tib.accessRights |
frei zug�nglich |
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