dc.identifier.uri |
http://dx.doi.org/10.15488/12354 |
|
dc.identifier.uri |
https://www.repo.uni-hannover.de/handle/123456789/12453 |
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dc.contributor.author |
Natke, Dominik
|
|
dc.contributor.author |
Preiss, Annika
|
|
dc.contributor.author |
Klimke, Stephen
|
|
dc.contributor.author |
Shiga, Takuya
|
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dc.contributor.author |
Boca, Roman
|
|
dc.contributor.author |
Ohba, Masaaki
|
|
dc.contributor.author |
Oshio, Hiroki
|
|
dc.contributor.author |
Renz, Franz
|
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dc.date.accessioned |
2022-06-27T04:37:00Z |
|
dc.date.available |
2022-06-27T04:37:00Z |
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dc.date.issued |
2021 |
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dc.identifier.citation |
Natke, D.; Preiss, A.; Klimke, S.; Shiga, T.; Boca, R. et al.: Structural, Magnetic, and Electrochemical Characterization of Iron(III) and Cobalt Complexes with Penta-N3O2-dentate Ligands. In: European Journal of Inorganic Chemistry 2021 (2021), Nr. 15, S. 1498-1504. DOI: https://doi.org/10.1002/ejic.202100081 |
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dc.description.abstract |
Six new mononuclear [FeIII(LBr,Cl)X]-complexes (LBr,Cl is the dianionic penta-N3O2-dentate Schiff base ligand N,N′-bis(2’-hydroxy-3-bromo-5-chlorobenzylidene)-1,6-diamino-3-azahexane; X: Cl−, N3−, NCO−, NCS−, NCSe−, CN−) were synthesized and their structures, magnetic and electrochemical properties studied. Structure analysis and magnetic measurements showed that [FeIII(LBr,Cl)CN] is in the low spin state and the other five complexes are in high spin states. Furthermore, the trinuclear mixed valent cobalt complex {[CoIII(LH,H)CN]2[CoII(1-methylimidazole)3(H2O)]} was prepared and its magnetic behavior studied. © 2021 The Authors. European Journal of Inorganic Chemistry published by Wiley-VCH GmbH |
eng |
dc.language.iso |
eng |
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dc.publisher |
Weinheim : Wiley-VCH |
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dc.relation.ispartofseries |
European Journal of Inorganic Chemistry 2021 (2021), Nr. 15 |
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dc.rights |
CC BY 4.0 Unported |
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dc.rights.uri |
https://creativecommons.org/licenses/by/4.0/ |
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dc.subject |
Cobalt |
eng |
dc.subject |
Iron |
eng |
dc.subject |
Magnetic properties |
eng |
dc.subject |
Mixed valance |
eng |
dc.subject |
Redox chemistry |
eng |
dc.subject |
Schiff base complexes |
eng |
dc.subject.ddc |
540 | Chemie
|
ger |
dc.title |
Structural, Magnetic, and Electrochemical Characterization of Iron(III) and Cobalt Complexes with Penta-N3O2-dentate Ligands |
|
dc.type |
Article |
|
dc.type |
Text |
|
dc.relation.essn |
1099-0682 |
|
dc.relation.doi |
https://doi.org/10.1002/ejic.202100081 |
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dc.bibliographicCitation.issue |
15 |
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dc.bibliographicCitation.volume |
2021 |
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dc.bibliographicCitation.firstPage |
1498 |
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dc.bibliographicCitation.lastPage |
1504 |
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dc.description.version |
publishedVersion |
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tib.accessRights |
frei zug�nglich |
|