dc.identifier.uri |
http://dx.doi.org/10.15488/10637 |
|
dc.identifier.uri |
https://www.repo.uni-hannover.de/handle/123456789/10715 |
|
dc.contributor.author |
Poock, Caroline
|
|
dc.contributor.author |
Kalesse, Markus
|
|
dc.date.accessioned |
2021-03-26T08:44:48Z |
|
dc.date.available |
2021-03-26T08:44:48Z |
|
dc.date.issued |
2020 |
|
dc.identifier.citation |
Poock, C.; Kalesse, M.: Total Synthesis and Structure Revision of Halioxepine. In: Chemistry - A European Journal 27 (2020), Nr. 5, S. 1615-1619. DOI: https://doi.org/10.1002/chem.202004847 |
|
dc.description.abstract |
The first total synthesis of halioxepine is accomplished using a 1,4-addition for constructing the quaternary center at C10 and a halo etherification for the generation of the tertiary ether at C7. The correct structure of halioxepine was determined by assembling different enantiomeric building blocks and by changing the relative configuration between C10 and C15. © 2020 The Authors. Published by Wiley-VCH GmbH |
eng |
dc.language.iso |
eng |
|
dc.publisher |
Weinheim : Wiley-VCH Verl. |
|
dc.relation.ispartofseries |
Chemistry - A European Journal 27 (2020), Nr. 5 |
|
dc.rights |
CC BY-NC-ND 4.0 Unported |
|
dc.rights.uri |
https://creativecommons.org/licenses/by-nc-nd/4.0/ |
|
dc.subject |
halo etherification |
eng |
dc.subject |
natural product synthesis |
eng |
dc.subject |
quaternary stereocenter |
eng |
dc.subject |
structure elucidation |
eng |
dc.subject |
terpenoids |
eng |
dc.subject.ddc |
540 | Chemie
|
ger |
dc.title |
Total Synthesis and Structure Revision of Halioxepine |
|
dc.type |
Article |
|
dc.type |
Text |
|
dc.relation.essn |
1521-3765 |
|
dc.relation.issn |
0947-6539 |
|
dc.relation.doi |
https://doi.org/10.1002/chem.202004847 |
|
dc.bibliographicCitation.issue |
5 |
|
dc.bibliographicCitation.volume |
27 |
|
dc.bibliographicCitation.firstPage |
1615 |
|
dc.bibliographicCitation.lastPage |
1619 |
|
dc.description.version |
publishedVersion |
|
tib.accessRights |
frei zug�nglich |
|