Towards Biochar and Hydrochar Engineering-Influence of Process Conditions on Surface Physical and Chemical Properties, Thermal Stability, Nutrient Availability, Toxicity and Wettability

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Dieguez-Alonso, A. et al.: Towards Biochar and Hydrochar Engineering-Influence of Process Conditions on Surface Physical and Chemical Properties, Thermal Stability, Nutrient Availability, Toxicity and Wettability. In: Energies 11 (2018), Nr. 3, 496. DOI: https://doi.org/10.3390/en11030496

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To cite the version in the repository, please use this identifier: https://doi.org/10.15488/4909

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Abstract: 
The impact of conversion process parameters in pyrolysis (maximum temperature, inert gas flow rate) and hydrothermal carbonization (maximum temperature, residence time and post-washing) on biochar and hydrochar properties is investigated. Pine wood (PW) and corn digestate (CD), with low and high inorganic species content respectively, are used as feedstock. CD biochars show lower H/C ratios, thermal recalcitrance and total specific surface area than PW biochars, but higher mesoporosity. CD and PW biochars present higher naphthalene and phenanthrene contents, respectively, which may indicate different reaction pathways. High temperatures (>500 degrees C) lead to lower PAH (polycyclic aromatic hydrocarbons) content (<12 mg/kg) and higher specific surface area. With increasing process severity the biochars carbon content is also enhanced, as well as the thermal stability. High inert gas flow rates increase the microporosity and wettability of biochars. In hydrochars the high inorganic content favor decarboxylation over dehydration reactions. Hydrochars show mainly mesoporosity, with a higher pore volume but generally lower specific surface area than biochars. Biochars present negligible availability of NO3- and NH4+, irrespective of the nitrogen content of the feedstock. For hydrochars, a potential increase in availability of NO3-, PO43-, and K+ with respect to the feedstock is possible. The results from this work can be applied to "engineer" appropriate biochars with respect to soil demands and certification requirements.
License of this version: CC BY 4.0 Unported
Document Type: Article
Publishing status: publishedVersion
Issue Date: 2018
Appears in Collections:Naturwissenschaftliche Fakultät

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pos. country downloads
total perc.
1 image of flag of Germany Germany 118 63.78%
2 image of flag of United States United States 31 16.76%
3 image of flag of China China 5 2.70%
4 image of flag of France France 4 2.16%
5 image of flag of Kenya Kenya 3 1.62%
6 image of flag of Iran, Islamic Republic of Iran, Islamic Republic of 3 1.62%
7 image of flag of India India 2 1.08%
8 image of flag of United Kingdom United Kingdom 2 1.08%
9 image of flag of Spain Spain 2 1.08%
10 image of flag of Switzerland Switzerland 2 1.08%
    other countries 13 7.03%

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