Mössbauer Spectroscopic Study and Magnetic Investigation of Iron(III) Complexes on a Dendrimeric Basis

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Nariaki, Driss; Lekovic, Faik; Homenya, Patrick; Renz, Franz: Mössbauer Spectroscopic Study and Magnetic Investigation of Iron(III) Complexes on a Dendrimeric Basis. In: Journal of Physics Conference Series 534 (2014), 12002. DOI: http://dx.doi.org/10.1088/1742-6596/534/1/012002

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Sum total of downloads: 195




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Abstract: 
The functionalization of the molecular surface of various dendrimer generations with a phosphorous core and external amine groups is obtained by converting those amine groups into the corresponding imines of salicylaldehyde creating multiple coordination sites for the iron atoms. Treatment with iron(III) chloride yields multinuclear iron(III) complexes on a dendrimeric basis. The obtained multinuclear molecular systems exhibit extremely high total spin values. The influence of the generation growth on this type of coordination compounds is investigated by Mossbauer spectroscopy and SQUIDmagnetometry.
License of this version: CC BY 3.0 Unported
Document Type: Article
Publishing status: publishedVersion
Issue Date: 2014
Appears in Collections:Naturwissenschaftliche Fakultät

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pos. country downloads
total perc.
1 image of flag of Germany Germany 143 73.33%
2 image of flag of United States United States 24 12.31%
3 image of flag of China China 8 4.10%
4 image of flag of United Kingdom United Kingdom 3 1.54%
5 image of flag of Europe Europe 3 1.54%
6 image of flag of Morocco Morocco 2 1.03%
7 image of flag of Sweden Sweden 1 0.51%
8 image of flag of Paraguay Paraguay 1 0.51%
9 image of flag of Netherlands Netherlands 1 0.51%
10 image of flag of Kazakhstan Kazakhstan 1 0.51%
    other countries 8 4.10%

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