Microwave-accelerated Mizoroki-Heck and Sonogashira cross- coupling reactions in water using a heterogeneous palladium(II)-precatalyst

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Dawood, K.M.; Solodenko, W.; Kirschning, A.: Microwave-accelerated Mizoroki-Heck and Sonogashira cross- coupling reactions in water using a heterogeneous palladium(II)-precatalyst. In: Arkivoc 2007 (2007), Nr. 5, S. 104-124. DOI: https://doi.org/10.3998/ark.5550190.0008.510

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Sum total of downloads: 131




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Abstract: 
The catalytic activity of a 2-pyridinealdoxime-based Pd(II)-complex covalently anchored via the oxime moiety to a glass/ polymer composite material was evaluated both under thermal as well as microwave (μw) irradiating conditions in water in Mizoroki-Heck as well as Sonogashira C-C cross-coupling reactions. Synthesis of benzo[b]furan derivatives via Sonogashira cross coupling reaction was achieved when ortho-halo-phenols were employed as aryl halides. The stability and reusability of this Pd-precatalyst was part of the present study.
License of this version: CC BY-NC 3.0 Unported
Document Type: Article
Publishing status: publishedVersion
Issue Date: 2007
Appears in Collections:Naturwissenschaftliche Fakultät

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pos. country downloads
total perc.
1 image of flag of Germany Germany 23 17.56%
2 image of flag of United States United States 17 12.98%
3 image of flag of Singapore Singapore 17 12.98%
4 image of flag of India India 10 7.63%
5 image of flag of Iran, Islamic Republic of Iran, Islamic Republic of 9 6.87%
6 image of flag of Pakistan Pakistan 6 4.58%
7 image of flag of Egypt Egypt 6 4.58%
8 image of flag of France France 5 3.82%
9 image of flag of China China 5 3.82%
10 image of flag of Japan Japan 4 3.05%
    other countries 29 22.14%

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