Microwave-accelerated Mizoroki-Heck and Sonogashira cross- coupling reactions in water using a heterogeneous palladium(II)-precatalyst

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Dawood, K.M.; Solodenko, W.; Kirschning, A.: Microwave-accelerated Mizoroki-Heck and Sonogashira cross- coupling reactions in water using a heterogeneous palladium(II)-precatalyst. In: Arkivoc 2007 (2007), Nr. 5, S. 104-124. DOI: https://doi.org/10.3998/ark.5550190.0008.510

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Abstract: 
The catalytic activity of a 2-pyridinealdoxime-based Pd(II)-complex covalently anchored via the oxime moiety to a glass/ polymer composite material was evaluated both under thermal as well as microwave (μw) irradiating conditions in water in Mizoroki-Heck as well as Sonogashira C-C cross-coupling reactions. Synthesis of benzo[b]furan derivatives via Sonogashira cross coupling reaction was achieved when ortho-halo-phenols were employed as aryl halides. The stability and reusability of this Pd-precatalyst was part of the present study.
License of this version: CC BY-NC 3.0 Unported
Document Type: article
Publishing status: publishedVersion
Issue Date: 2007
Appears in Collections:Naturwissenschaftliche Fakultät

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pos. country downloads
total perc.
1 image of flag of Singapore Singapore 16 21.62%
2 image of flag of Germany Germany 14 18.92%
3 image of flag of India India 7 9.46%
4 image of flag of Egypt Egypt 6 8.11%
5 image of flag of Iran, Islamic Republic of Iran, Islamic Republic of 5 6.76%
6 image of flag of France France 3 4.05%
7 image of flag of Iraq Iraq 2 2.70%
8 image of flag of China China 2 2.70%
9 image of flag of Switzerland Switzerland 2 2.70%
10 image of flag of Australia Australia 2 2.70%
    other countries 15 20.27%

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