We introduce a new framework for a descriptive complexity approach to arithmetic computations. We define a hierarchy of classes based on the idea of counting assignments to free function variables in first-order formulae. We completely determine the inclusion structure and show that #P and #AC0 appear as classes of this hierarchy. In this way, we unconditionally place #AC0 properly in a strict hierarchy of arithmetic classes within #P. We compare our classes with a hierarchy within #P defined in a model-theoretic way by Saluja et al. We argue that our approach is better suited to study arithmetic circuit classes such as #AC0 which can be descriptively characterized as a class in our framework.