High pressure chiral recognition experiments - A route to homochiral 4-fluorocyclohexenones

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Meibom, D.; Weinmann, H.; Winterfeldt, E.: High pressure chiral recognition experiments - A route to homochiral 4-fluorocyclohexenones. In: Arkivoc 2004 (2004), Nr. 2, S. 4-23

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Sum total of downloads: 62




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Abstract: 
4-Fluorocyclohexadienones, prepared by an improved Jacquesy-process, were shown to undergo highly face-selective Diels-Alder reactions with the homochiral cyclopentadiene 1. Some of the diastereoselective transformations, quite unique rearrangements of ?-hydroxy compounds resulting from nucleophilic attack to the carbonyl group as well as selected Retro-Diels-Alder reactions, are reported.
License of this version: CC BY-NC 3.0 Unported
Document Type: Article
Publishing status: publishedVersion
Issue Date: 2004
Appears in Collections:Naturwissenschaftliche Fakultät

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pos. country downloads
total perc.
1 image of flag of Germany Germany 34 54.84%
2 image of flag of United States United States 7 11.29%
3 image of flag of Vietnam Vietnam 6 9.68%
4 image of flag of China China 4 6.45%
5 image of flag of Japan Japan 3 4.84%
6 image of flag of United Kingdom United Kingdom 3 4.84%
7 image of flag of Netherlands Netherlands 2 3.23%
8 image of flag of Taiwan Taiwan 1 1.61%
9 image of flag of Spain Spain 1 1.61%
10 image of flag of Canada Canada 1 1.61%

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