Synthetic Applications of Oxidative Aromatic Coupling : From Biphenols to Nanographenes

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Grzybowski, M.; Sadowski, B.; Butenschön, H.; Gryko, D.T.: Synthetic Applications of Oxidative Aromatic Coupling : From Biphenols to Nanographenes. In: Angewandte Chemie - International Edition 59 (2019), Nr. 8, S. 2998-3027. DOI:

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Sum total of downloads: 69

Oxidative aromatic coupling occupies a fundamental place in the modern chemistry of aromatic compounds. It is a method of choice for the assembly of large and bewildering architectures. Considerable effort was also devoted to applications of the Scholl reaction for the synthesis of chiral biphenols and natural products. The ability to form biaryl linkages without any prefunctionalization provides an efficient pathway to many complex structures. Although the chemistry of this process is only now becoming fully understood, this reaction continues to both fascinate and challenge researchers. This is especially true for heterocoupling, that is, oxidative aromatic coupling with the chemoselective formation of a C−C bond between two different arenes. Analysis of the progress achieved in this field since 2013 reveals that many groups have contributed by pushing the boundary of structural possibilities, expanding into surface‐assisted (cyclo)dehydrogenation, and developing new reagents.
License of this version: CC BY 4.0 Unported
Document Type: Article
Publishing status: publishedVersion
Issue Date: 2019
Appears in Collections:Naturwissenschaftliche Fakultät

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pos. country downloads
total perc.
1 image of flag of Germany Germany 26 37.68%
2 image of flag of United States United States 21 30.43%
3 image of flag of China China 7 10.14%
4 image of flag of No geo information available No geo information available 6 8.70%
5 image of flag of Seychelles Seychelles 2 2.90%
6 image of flag of Taiwan Taiwan 1 1.45%
7 image of flag of Netherlands Netherlands 1 1.45%
8 image of flag of Malawi Malawi 1 1.45%
9 image of flag of Luxembourg Luxembourg 1 1.45%
10 image of flag of India India 1 1.45%
    other countries 2 2.90%

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