CdS crown growth on CdSe nanoplatelets : Core shape matters

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Schlosser, A.; Graf, R.T.; Bigall, N.C.: CdS crown growth on CdSe nanoplatelets : Core shape matters. In: Nanoscale Advances 2 (2020), Nr. 10, S. 4604-4614. DOI: https://doi.org/10.1039/d0na00619j

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Sum total of downloads: 105




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Abstract: 
Cadmium chalcogenide nanoplatelets (NPLs) have gained tremendous attention in the past decade due to their extremely narrow optical features and their special electronic properties. For the application of the NPLs as optical emitters, in (photo) catalysis or sensing, further modification of the pristine (core) NPLs can be required. Therefore, many procedures for the synthesis of crowns (lateral extension of the core NPLs), shells and particle domains on the NPLs have already been developed. CdSe/CdS core/crown NPLs are characterised by extremely short photoluminescence (PL) lifetimes and high PL quantum yields (PLQYs) and might therefore be ideal candidates for lighting applications. In this work, we show how the optical properties of CdSe/CdS core/crown NPLs, especially their PLQYs, can be strongly improved by applying a sulphur precursor with a low reactivity. Under optimised conditions, the new procedure allows the growth of uniform CdS crowns around CdSe core NPLs with various lateral sizes, thicknesses and shapes. In addition, the modified growth kinetics was investigated by various methods, including UV/vis and PL spectroscopy as well as transmission electron microscopy. This journal is © The Royal Society of Chemistry.
License of this version: CC BY-NC 3.0 Unported
Document Type: Article
Publishing status: publishedVersion
Issue Date: 2020
Appears in Collections:Naturwissenschaftliche Fakultät

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pos. country downloads
total perc.
1 image of flag of Germany Germany 59 56.19%
2 image of flag of United States United States 22 20.95%
3 image of flag of Turkey Turkey 5 4.76%
4 image of flag of Russian Federation Russian Federation 5 4.76%
5 image of flag of China China 5 4.76%
6 image of flag of India India 2 1.90%
7 image of flag of France France 2 1.90%
8 image of flag of Canada Canada 2 1.90%
9 image of flag of Vietnam Vietnam 1 0.95%
10 image of flag of Netherlands Netherlands 1 0.95%
    other countries 1 0.95%

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