Understanding electrical under- and overshoots in proton exchange membrane water electrolysis cells

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Immerz, C.; Bensmann, B.; Trinke, P.; Suermann, M.; Hanke-Rauschenbach, R.: Understanding electrical under- and overshoots in proton exchange membrane water electrolysis cells. In: Journal of the Electrochemical Society 166 (2019), Nr. 15, S. F1200-F1208. DOI: https://doi.org/10.1149/2.0881914jes

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Sum total of downloads: 229




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Abstract: 
Ability of dynamic operation seems to be an important feature of proton exchange membrane water electrolyzers (PEMWE) to become a relevant part of the future energy system. However, only few fundamental analyzes of the dynamic behavior on short time scales are available in the literature. Therefore, this contribution aims to give insights into the most fundamental transient behavior of a PEMWE cell by an experimental analysis on the laboratory scale and a model based description of the ongoing phenomena. Experimental voltage and current controlled load step are carried out and analyzed by methods adapted from fuel cell characterization. The experimental analysis revealed that load steps are a combination of an instantaneous characteristic followed by dynamics of higher order dependent on activation, mass transfer and temperature effects. Potentiostatic downward steps to very low cell voltages can lead to current density reversal phenomena with highly negative peak current densities. By means of a simple prototype model analysis, these reversal processes are analyzed and the consequences of the phenomena are estimated. The simulation results indicate that a reversal of the cell current density can be attributed to a change of capacitive rather than faradaic currents, meaning that internal electrolysis processes are not involved. © The Author(s) 2019. Published by ECS.
License of this version: CC BY 4.0 Unported
Document Type: Article
Publishing status: publishedVersion
Issue Date: 2019
Appears in Collections:Fakultät für Elektrotechnik und Informatik

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pos. country downloads
total perc.
1 image of flag of Germany Germany 98 42.79%
2 image of flag of United States United States 45 19.65%
3 image of flag of China China 24 10.48%
4 image of flag of Turkey Turkey 7 3.06%
5 image of flag of Korea, Republic of Korea, Republic of 7 3.06%
6 image of flag of Russian Federation Russian Federation 4 1.75%
7 image of flag of Japan Japan 4 1.75%
8 image of flag of France France 4 1.75%
9 image of flag of India India 3 1.31%
10 image of flag of Denmark Denmark 3 1.31%
    other countries 30 13.10%

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