Browsing by Subject "meroterpenoid"

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  • Stereochemical and Biosynthetic Rationalisation of the Tropolone Sesquiterpenoids 
    Li, Lei; Cox, Russell J. (Basel : MDPI, 2022)
    This review summarises the known structures, biological activities, and biosynthetic pathways of the tropolone sesquiterpenoid family of fungal secondary metabolites. Synthesis of this knowledge allows likely structural ...
  • Studien zur Totalsynthese von Yaminterritrem A 
    Hoffmann, Timo (Hannover : Institutionelles Repositorium der Leibniz Universität Hannover, 2020)
    Die vorliegende Dissertation beschäftigt sich mit den Studien zur ersten Totalsynthese von Yaminterritrem A. Bei dem komplexen Naturstoff handelt es sich um ein Meroterpenoid, das 2015 aus dem Schimmelpilz Aspergillus ...
  • Synthetic Biology Driven Biosynthesis of Unnatural Tropolone Sesquiterpenoids 
    Schotte, Carsten; Li, Lei; Wibberg, Daniel; Kalinowski, Jörn; Cox, Russell J. (Weinheim : Wiley-VCH Verl., 2020)
    Tropolone sesquiterpenoids (TS) are an intriguing family of biologically active fungal meroterpenoids that arise through a unique intermolecular hetero Diels–Alder (hDA) reaction between humulene and tropolones. Here, we ...
  • Understanding and Engineering the Stereoselectivity of Humulene Synthase 
    Schotte, Carsten; Lukat, Peer; Deuschmann, Adrian; Blankenfeldt, Wulf; Cox, Russell J. (Weinheim : Wiley-VCH, 2021)
    The non-canonical terpene cyclase AsR6 is responsible for the formation of 2E,6E,9E-humulene during the biosynthesis of the tropolone sesquiterpenoid (TS) xenovulene A. The structures of unliganded AsR6 and of AsR6 in ...