Browsing by Subject "Vinyl azides"

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[3 + 2]-Cycloadditions of nitrile ylides after photoactivion of vinyl azides under flow conditions

Cludius-Brandt, Stephan; Kupracz, Lukas; Kirschning, Andreas (Frankfurt am Main : Beilstein-Institut zur Förderung der Chemischen Wissenschaften, 2013)

The photodenitrogenation of vinyl azides to 2H-azirines by using a photoflow reactor is reported and compared with thermal formation of 2H-azirines. Photochemically, the ring of the 2H-azirines was opened to yield the ...
Multistep flow synthesis of vinyl azides and their use in the copper-catalyzed huisgen-type cycloaddition under inductive-heating conditions

Kupracz, Lukas; Hartwig, Jan; Wegner, Jens; Ceylan, Sascha; Kirschning, Andreas (Frankfurt am Main : Beilstein-Institut Zur Förderung der Chemischen Wissenschaften, 2011)

The multistep flow synthesis of vinyl azides and their application in the synthesis of vinyltriazoles is reported. The synthesis relies on a stable polymer-bound equivalent of iodine azide that serves to carry out ...

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