Browsing by Subject "Iron complex"

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  • Molecular switching in iron complexes bridged via tin-cyanides observed by Mössbauer and ESR spectroscopy 
    Jung, S.; Renz, Franz; Klein, M.; Menzel, M.; Boča, R.; Stößer, R. (Bristol : IOP Publishing Ltd., 2010)
    The precursor [FeIII(L)Cl] (LH2 N,N'-bis(2'-hydroxy- 3'-X-benzyliden)-1,6-diamino-3-N-hexane) is a high-spin (S 5/2) complex (with X -CH3, -O-CH3). This precursor is combined with the bridging unit [SnIV(CN)4] to yield ...
  • A rectangular Ni-Fe cluster with unusual cyanide bridges 
    Krüger, Christoph; Sato, Hiroki; Matsumoto, Takuto; Shiga, Takuya; Newton, Graham N.; Renz, Franz; Oshio, Hiroki (Cambridge : Royal Society of Chemistry, 2012)
    An asymmetric polycyanide iron complex, K2[Fe III(L1)(CN)4](MeOH) (HL1 = 2,2′-(1H-pyrazole-3,5- diyl)bis-pyridine), was synthesized and its complexation compatibility with nickel ions was examined. Two kinds of enantiomeric ...