dc.identifier.uri |
http://dx.doi.org/10.15488/14659 |
|
dc.identifier.uri |
https://www.repo.uni-hannover.de/handle/123456789/14777 |
|
dc.contributor.author |
Nikolaiczyk, Vanessa
|
|
dc.contributor.author |
Kirschning, Andreas
|
|
dc.contributor.author |
Díaz, Edison
|
|
dc.date.accessioned |
2023-09-01T05:45:20Z |
|
dc.date.available |
2023-09-01T05:45:20Z |
|
dc.date.issued |
2022 |
|
dc.identifier.citation |
Nikolaiczyk, V.; Kirschning, A.; Díaz, E.: Lipoxygenase-catalysed co-oxidation for sustained production of oxyfunctionalized terpenoids. In: Flavour and Fragrance Journal 37 (2022), Nr. 4, S. 234-242. DOI: https://doi.org/10.1002/ffj.3700 |
|
dc.description.abstract |
Lipoxygenases (LOX) catalyse allylic oxidations and epoxidations of a co-substrate in the presence of an unsaturated fatty acid containing a 1,4-pentadiene moiety. One- and two-step enzyme assays were established to verify the role or involvement of LOX in such co-oxidations. It was shown that LOX is only involved in the formation of reactive hydroperoxides, but not in the oxidation of a co-substrate, assuming a mechanism involving free peroxy radicals for the latter. Ten mono- and sesquiterpenes were used as co-substrates and the resulting products were analysed by mass spectrometry. A semi-preparative approach was developed using (+)-valencene as an example, and the resulting products were isolated by preparative GC and their structures elucidated by NMR spectroscopy. |
eng |
dc.language.iso |
eng |
|
dc.publisher |
New York, NY [u.a.] : Wiley |
|
dc.relation.ispartofseries |
Flavour and Fragrance Journal 37 (2022), Nr. 4 |
|
dc.rights |
CC BY-NC-ND 4.0 Unported |
|
dc.rights.uri |
https://creativecommons.org/licenses/by-nc-nd/4.0 |
|
dc.subject |
lipoxygenase |
eng |
dc.subject |
nootkatone |
eng |
dc.subject |
oxidation |
eng |
dc.subject |
terpenes |
eng |
dc.subject |
valencene |
eng |
dc.subject.ddc |
660 | Technische Chemie
|
|
dc.subject.ddc |
540 | Chemie
|
|
dc.title |
Lipoxygenase-catalysed co-oxidation for sustained production of oxyfunctionalized terpenoids |
eng |
dc.type |
Article |
|
dc.type |
Text |
|
dc.relation.essn |
1099-1026 |
|
dc.relation.issn |
0882-5734 |
|
dc.relation.doi |
https://doi.org/10.1002/ffj.3700 |
|
dc.bibliographicCitation.issue |
4 |
|
dc.bibliographicCitation.volume |
37 |
|
dc.bibliographicCitation.firstPage |
234 |
|
dc.bibliographicCitation.lastPage |
242 |
|
dc.description.version |
publishedVersion |
eng |
tib.accessRights |
frei zug�nglich |
|