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Original version
Marshall, J.W.; De Mattos-Shipley, K.M.J.; Ghannam, I.A.Y.; Munawar, A.; Killen, J.C. et al.: Fusarochromene, a novel tryptophan-derived metabolite from: Fusarium sacchari. In: Organic and Biomolecular Chemistry 19 (2021), Nr. 1, S. 182-187. DOI: https://doi.org/10.1039/d0ob02031a
Repository version
To cite the version in the repository, please use this identifier:
https://doi.org/10.15488/14506
Files in this item
| Abstract: | |
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Fusarochromene isolated from the plant pathogenic fungus, Fusarium sacchari is closely related to a group of mycotoxins including fusarochromanone previously isolated from various Fusaria spp. Despite their assumed polyketide biogenesis, incorporation studies with 13C-labelled acetate, glycerol and tryptophans show that fusarochromene is unexpectedly derived via oxidative cleavage of the aromatic amino acid tryptophan. A putative biosynthetic gene cluster has been identified.
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| License of this version: | CC BY-NC 3.0 Unported - https://creativecommons.org/licenses/by-nc/3.0 |
| Publication type: | Article |
| Publishing status: | publishedVersion |
| Publication date: | 2020 |
| Keywords english: | Fusarium, Multigene Family, Oxidation-Reduction, Tryptophan, Amino acids |
| DDC: | 540 | Chemie |
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Naturwissenschaftliche Fakultät
Frei zugängliche Publikationen aus der Naturwissenschaftlichen Fakultät