Abstract: |
Oxidative rearrangements are key reactions during the biosyntheses of many secondary metabolites in fungi. This review highlights the most important examples of these reactions and aims to draw together key mechanistic themes to allow a better understanding and future exploitation of this key class of fungal catalysts.
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License of this version: |
CC BY-NC 3.0 Unported - http://creativecommons.org/licenses/by-nc/3.0/
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Publication type: |
Article |
Publishing status: |
publishedVersion |
Publication date: |
2014-07-25 |
Keywords german: |
Cephalosporine, Cephalosporine C, Biosynthese, Cephalosporine C-Biosynthese, Kernmagnetische Resonanz, Kernspinresonanz, zellfreier Extrakt, Rohextrakt, Aflatoxin, Aflatoxin-Biosynthese, Ringerweiterung, Aspergillus nidulans, Gießkannenschimmel, Penicillin N, Desacetoxycephalosporin C, Heterologe Expression, Polyketid, Polyketid-Biosynthese
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Keywords english: |
cephalosporin-c biosynthesis, nuclear-magnetic-resonance, cell-free-extracts, aflatoxin biosynthesis, ring-expansion, aspergillus-nidulans, penicillin-n, deacetoxycephalosporin-c, heterologous expression, polyketide biosynthesis
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DDC: |
540 | Chemie, 570 | Biowissenschaften, Biologie
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Controlled keywords(GND): |
Cephalosporin C, Biosynthese, Magnetische Kernresonanz, Extrakt, Aflatoxin, Ringerweiterung <Chemie>, Aspergillus nidulans, Penicilline, Heterologe Genexpression
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