Limitation of industrial phosphorus-diffused emitters by SRH recombination

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Mina, B.; Wagner, H.; Dastgheib-Shirazi, A.; Altermatt, P.P.: Limitation of industrial phosphorus-diffused emitters by SRH recombination. In: Energy Procedia 55 (2014), S. 115-120. DOI: https://doi.org/10.1016/j.egypro.2014.08.090

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Sum total of downloads: 161




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Abstract: 
It is commonly assumed in the PV community that Auger recombination is the dominant loss mechanism in heavily phosphorusdoped emitters of industrial Si solar cells. Contrary to this assumption, we show in this work that most of the losses are caused by Shockley-Read-Hall (SRH) recombination via defect states introduced by inactive phosphorus. Using numerical device simulations, we successfully reproduce all the measured J0e values of a series of profiles (with various concentrations of inactive phosphorus) with an effective SRH capture crosses-section for holes, σp = 7.5×10-18 cm2. The composition of inactive phosphorus (e.g. in form of clusters of interstitial phosphorus, fine and rod-shaped precipitates) may vary under different fabrication conditions, hence we do not claim that this σp value is globally valid. However, because the series of profiles is representative for many emitters in mass production, our result implies generally higher SRH than Auger recombination rates and has decisive implications on the improvement of such industrial emitters: many emitters have not yet reached the Auger-limit and they may still be significantly improved by reducing their density of inactive phosphorus.
License of this version: CC BY-NC-ND 3.0 Unported
Document Type: Article
Publishing status: publishedVersion
Issue Date: 2014
Appears in Collections:Fakultät für Mathematik und Physik

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pos. country downloads
total perc.
1 image of flag of Germany Germany 105 65.22%
2 image of flag of United States United States 20 12.42%
3 image of flag of China China 14 8.70%
4 image of flag of Indonesia Indonesia 4 2.48%
5 image of flag of Taiwan Taiwan 3 1.86%
6 image of flag of Latvia Latvia 2 1.24%
7 image of flag of Korea, Republic of Korea, Republic of 2 1.24%
8 image of flag of Europe Europe 2 1.24%
9 image of flag of Brazil Brazil 2 1.24%
10 image of flag of Japan Japan 1 0.62%
    other countries 6 3.73%

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