Carrier lifetime instabilities in the bulk and at the surfaces of crystalline silicon solar cells triggered by fast-firing processes

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Winter, Michael: Carrier lifetime instabilities in the bulk and at the surfaces of crystalline silicon solar cells triggered by fast-firing processes. Hannover : Gottfried Wilhelm Leibniz Univ., Diss., 2024, vi, 115, XIV S., DOI: https://doi.org/10.15488/16952

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Abstract: 
Carrier lifetime instabilities in crystalline silicon solar cells under illumination affectthe long-term stability of photovoltaic modules in view of the steadily increasingconversion efficiency of the solar cells used in state-of-the-art modules. This thesisexamines carrier lifetime degradation and regeneration – both in the bulk and atthe surfaces of different crystalline silicon materials and solar cells made thereof –after a fast-firing step has been applied in a conveyor belt furnace. It is shownthat fast-firing triggers degradation effects under illumination. However, fast-firingis also a key step in the contact formation of screen-printed contacts, which is thedominating metalization technique applied today in the solar cell production.Independent of fast-firing in a standard conveyor belt furnace, the bulk carrierlifetime of boron-doped Czochralski-grown silicon (Cz-Si:B) is dominated by thelight-induced activation of a boron-oxygen (BO) defect. Gallium-doped Czochralski-grown silicon (Cz-Si:Ga) and boron-doped float-zone silicon (FZ-Si:B) – both notprone to BO-related degradation –, however, show a strongly temperature-dependent degradation of the bulk lifetime activated under simultaneous illumination. The equilibrium state establishing between activated (recombination-active) and deactivated (recombination-inactive) state of the defect is dependent on the temperature and the activation and deactivation of the defect are reversible processes. It is shown that the in-diffusion of hydrogen from hydrogen-rich silicon nitride layers (SiNy:H), used for the surface passivation and as antireflection coating, into the silicon bulk during fast firing plays a key role for the so-called ”light- and elevated-temperature-induced degradation”(LeTID) in all three materials – namely Cz-Si:B, Cz-Si:Ga, and FZ-Si:B. Experiments on the very defect-lean FZ-Si:B material furthermore suggest a second participant in the defect reaction of LeTID besides hydrogen.LeTID is also observed on ”polycrystalline silicon on oxide” (POLO) backjunction(BJ) solar cells fabricated on Cz-Si:Ga. The maximum relative degradation extentof the conversion efficiency η of only 2%rel at 140 °C and 1 sun, however, shows that POLO BJ cells are remarkably stable regarding light-induced degradation. Through prolonged illumination at elevated temperatures a partial permanent deactivation of the LeTID defect is possible.In addition to bulk degradation, thermally-induced instabilities of the phosphorus-doped POLO passivation layers after fast-firing are discovered. The degradationand the following regeneration of the surface passivation quality – described by thesaturation current density J0 – is correlated with high probability with the hydrogenpassivation of interface states.
License of this version: CC BY 3.0 DE
Document Type: DoctoralThesis
Publishing status: publishedVersion
Issue Date: 2024
Appears in Collections:Fakultät für Mathematik und Physik
Dissertationen

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5 image of flag of Algeria Algeria 5 5.88%
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    other countries 7 8.24%

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