Search engines are normally not designed to support human learning intents and processes. The field of Search as Learning (SAL) aims to investigate the characteristics of a successful Web search with a learning purpose. In this paper, we analyze the impact of text complexity of Web pages on predicting knowledge gain during a search session. For this purpose, we conduct an experimental case study and investigate the influence of several text-based features and classifiers on the prediction task. We build upon data from a study of related work, where 104 participants were given the task to learn about the formation of lightning and thunder through Web search. We perform an extensive evaluation based on a state-of-the-art approach and extend it with additional features related to textual complexity of Web pages. In contrast to prior work, we perform a systematic search for optimal hyperparameters and show the possible influence of feature selection strategies on the knowledge gain prediction. When using the new set of features, state-of-the-art results are noticeably improved. The results indicate that text complexity of Web pages could be an important feature resource for knowledge gain prediction.