Boosting the zinc storage of a small-molecule organic cathode by a desalinization strategy

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Wang, W.; Tang, Y.; Liu, J.; Li, H.; Wang, R. et al.: Boosting the zinc storage of a small-molecule organic cathode by a desalinization strategy. In: Chemical Science 14 (2023), Nr. 34, S. 9033-9040. DOI: https://doi.org/10.1039/d3sc03435f

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Abstract: 
Organic materials offer great potential as electrodes for batteries due to their high theoretical capacity, flexible structural design, and easily accessible materials. However, one significant drawback of organic electrode materials is their tendency to dissolve in the electrolyte. Resazurin sodium salt (RSS) has demonstrated remarkable charge/discharge performance characterized by a voltage plateau and high capacity when utilized as a cathode in aqueous zinc-ion batteries (AZIBs). Unfortunately, the solubility of RSS as a sodium salt continues to pose challenges in AZIBs. In this study, we introduce an RSS-containing organic compound, triresazurin-triazine (TRT), with a porous structure prepared by a desalinization method from the RSS and 2,4,6-trichloro-1,3,5-triazine (TCT). This process retained active groups (carbonyl and nitroxide radical) while generating a highly conjugated structure, which not only inhibits the dissolution in the electrolyte, but also improves the electrical conductivity, enabling TRT to have excellent electrochemical properties. When evaluated as a cathode for AZIBs, TRT exhibits a high reversible capacity of 180 mA h g−1, exceptional rate performance (78 mA h g−1 under 2 A g−1), and excellent cycling stability with 65 mA h g−1 at 500 mA g−1 after 1000 cycles.
License of this version: CC BY-NC 3.0 Unported
Document Type: Article
Publishing status: publishedVersion
Issue Date: 2023
Appears in Collections:Fakultät für Mathematik und Physik
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2 image of flag of No geo information available No geo information available 3 15.00%
3 image of flag of United States United States 3 15.00%
4 image of flag of United Kingdom United Kingdom 2 10.00%
5 image of flag of Thailand Thailand 1 5.00%
6 image of flag of Indonesia Indonesia 1 5.00%
7 image of flag of China China 1 5.00%

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