Bottling Liquid-Like Minerals for Advanced Materials Synthesis

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Gindele, M.B.; Nolte, S.; Stock, K.M.; Kebel, K.; Gebauer, D. Bottling Liquid-Like Minerals for Advanced Materials Synthesis. In: Advanced Materials 35 (2023), Nr. 25, 2300702. DOI: https://doi.org/10.1002/adma.202300702

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Sum total of downloads: 38




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Abstract: 
Materials synthesis via liquid-like mineral precursors has been studied since their discovery almost 25 years ago, because their properties offer several advantages, for example, the ability to infiltrate small pores, the production of non-equilibrium crystal morphologies or mimicking textures from biominerals, resulting in a vast range of possible applications. However, the potential of liquid-like precursors has never been fully tapped, and they have received limited attention in the materials chemistry community, largely due to the lack of efficient and scalable synthesis protocols. Herein, the “scalable controlled synthesis and utilization of liquid-like precursors for technological applications” (SCULPT) method is presented, allowing the isolation of the precursor phase on a gram scale, and its advantage in the synthesis of crystalline calcium carbonate materials and respective applications is demonstrated. The effects of different organic and inorganic additives, such as magnesium ions and concrete superplasticizers, on the stability of the precursor are investigated and allow optimizing the process for specific demands. The presented method is easily scalable and therefore allows synthesizing and utilizing the precursor on large scales. Thus, it can be employed for mineral formation during restoration and conservation applications but can also open up pathways toward calcium carbonate-based, CO2-neutral cements.
License of this version: CC BY-NC 4.0 Unported
Document Type: Article
Publishing status: publishedVersion
Issue Date: 2023
Appears in Collections:Naturwissenschaftliche Fakultät

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pos. country downloads
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1 image of flag of Germany Germany 17 44.74%
2 image of flag of United States United States 15 39.47%
3 image of flag of Russian Federation Russian Federation 1 2.63%
4 image of flag of Spain Spain 1 2.63%
5 image of flag of Estonia Estonia 1 2.63%
6 image of flag of Czech Republic Czech Republic 1 2.63%
7 image of flag of China China 1 2.63%
8 image of flag of Canada Canada 1 2.63%

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