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The angular overlap model extended for two-open-shell f and d electrons

Ramanantoanina, Harry; Urland, Werner; Cimpoesu, Fanica; Daul, Claude (Cambridge : Royal Society of Chemistry, 2014-05-01)

We discuss the applicability of the Angular Overlap Model (AOM) to evaluate the electronic structure of lanthanide compounds, which are currently the subject of incredible interest in the field of luminescent materials. ...
Characterization of powellite-based solid solutions by site-selective time resolved laser fluorescence spectroscopy

Schmidt, Moritz; Heck, Stephanie; Bosbach, Dirk; Ganschow, Steffen; Walther, Clemens; Stumpf, Thorsten (Cambridge : Royal Society of Chemistry, 2013)

We present a comprehensive study of the solid solution system Ca-2(MoO4)(2)-NaGd(MoO4)(2) on the molecular scale, by means of site-selective time resolved laser fluorescence spectroscopy (TRLFS). Eu3+ is used as a trace ...
Ligand field density functional theory for the prediction of future domestic lighting

Ramanantoanina, Harry; Urland, Werner; Garcia-Fuente, Amador; Cimpoesu, Fanica; Daul, Claude (Cambridge : Royal Society of Chemistry, 2014-05-13)

We deal with the computational determination of the electronic structure and properties of lanthanide ions in complexes and extended structures having open-shell f and d configurations. Particularly, we present conceptual ...
A luminescence line-narrowing spectroscopic study of the uranium(VI) interaction with cementitious materials and titanium dioxide

Tits, Jan; Walther, Clemens; Stumpf, Thorsten; Mace, Nathalie; Wieland, Erich (Cambridge : Royal Society of Chemistry, 2015)

Non-selective luminescence spectroscopy and luminescence line-narrowing spectroscopy were used to study the retention of UO22+ on titanium dioxide (TiO2), synthetic calcium silicate hydrate (C-S-H) phases and hardened ...

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