dc.identifier.uri | http://dx.doi.org/10.15488/2477 | |
dc.identifier.uri | http://www.repo.uni-hannover.de/handle/123456789/2503 | |
dc.contributor.author | Nuber, B. | |
dc.contributor.author | Weiss, J. | |
dc.contributor.author | Wieghardt, K. | |
dc.date.accessioned | 2017-11-24T12:08:39Z | |
dc.date.available | 2017-11-24T12:08:39Z | |
dc.date.issued | 1978 | |
dc.identifier.citation | Nuber, B.; Weiss, J.; Wieghardt, K.: Schwingungsspektrum und Kristallstruktur des fünffach-koordinierten cis-Dioxo-dipicolinato-vanadat(V)-Anions. In: Zeitschrift für Naturforschung - Section B Journal of Chemical Sciences 33 (1978), Nr. 3, S. 365-367. DOI: https://doi.org/10.1515/znb-1978-0303 | |
dc.description.abstract | cis-Dioxo-dipicolinato-vanadate(V), Crystal Structure, IR, Raman The crystal structure of Cs[V(O)2(dipic)]·H2O (dipic = pyridine-2,6-dicarboxylate) has been determined by single crystal x-ray diffraction analysis. The compound crystallizes in the monoclinic space group P21/a, with cell constants a =737.8(3), 6=1917.5(5), c = 792.9(3) pm, β= 94.87(6)°, and Z = 4. The geometry about vanadium is a distorted trigonal bipyramid containing a cis-dioxo moiety (∢ O-V-O 109.9(3)°, V=O bond lengths 161.0(6) and 161.5(6) pm). Vibrational absorptions νs(V - 0) and νas(V=O) were found at 956 and 947 cm-1 in the IR and Raman spectrum, resp. | eng |
dc.language.iso | ger | |
dc.publisher | Berlin : De Gruyter | |
dc.relation.ispartofseries | Zeitschrift für Naturforschung - Section B Journal of Chemical Sciences 33 (1978), Nr. 3 | |
dc.rights | CC BY-NC-ND 3.0 Unported | |
dc.rights.uri | https://creativecommons.org/licenses/by-nc-nd/3.0/ | |
dc.subject | cis-Dioxo-dipicolinato-vanadate(V) | eng |
dc.subject | Crystal Structure | eng |
dc.subject | IR | eng |
dc.subject | Raman | eng |
dc.subject.ddc | 540 | Chemie | ger |
dc.title | Schwingungsspektrum und Kristallstruktur des fünffach-koordinierten cis-Dioxo-dipicolinato-vanadat(V)-Anions | ger |
dc.type | Article | |
dc.type | Text | |
dc.relation.essn | 1865-7117 | |
dc.relation.issn | 0932-0776 | |
dc.relation.doi | https://doi.org/10.1515/znb-1978-0303 | |
dc.bibliographicCitation.issue | 3 | |
dc.bibliographicCitation.volume | 33 | |
dc.bibliographicCitation.firstPage | 365 | |
dc.bibliographicCitation.lastPage | 367 | |
dc.description.version | publishedVersion | |
tib.accessRights | frei zug�nglich |
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