dc.identifier.uri | http://dx.doi.org/10.15488/2454 | |
dc.identifier.uri | http://www.repo.uni-hannover.de/handle/123456789/2480 | |
dc.contributor.author | du Bois, André | |
dc.contributor.author | Abriel, Walter | |
dc.date.accessioned | 2017-11-24T10:48:03Z | |
dc.date.available | 2017-11-24T10:48:03Z | |
dc.date.issued | 1988 | |
dc.identifier.citation | du Bois, A.; Abriel, W.: Zur Stereochemie des freien Elektronenpaares in AX6E-Systemen, VIII Statisch verzerrte Anionen in [H3N(CH2)3NH3]3(BiX6)2(H2O)2 mit X = Cl, Br. In: Zeitschrift für Naturforschung - Section B Journal of Chemical Sciences 43 (1988), Nr. 8, S. 1003-1009. DOI: https://doi.org/10.1515/znb-1988-0815 | |
dc.description.abstract | Using 293 K diffractometer intensity data, the crystal structures of [H3N(CH2)3NH3]3(BiX6)2(H2O)2 with X - Cl, Br have been determined by single crystal X-ray technique and refined to a final Rw of 0.027 and 0.043, respectively. The structures are isotypic, space group P21/c, Z = 2 with a = 14.415(1). b = 9.7401(7), c = 12.4609(9)Å, β = 105.997(8)°for X - Cl and a = 14.794(2), b = 10.127(2), c = 12.853(2)Å, β = 105.68(2)° for X - Br. Statically distorted BiX63- octahedra confirm the symmetry rules for the stereochemistry of the lone pair electrons in AX6E-systems. Basic structural data for all compounds containing BiX63- and SbXh3 ions (X = Cl, Br, I) known to date are given including the ⊿-values as a measure for the distortion of the octahedral coordination polyhedron. | eng |
dc.language.iso | ger | |
dc.publisher | Berlin : De Gruyter | |
dc.relation.ispartofseries | Zeitschrift für Naturforschung - Section B Journal of Chemical Sciences 43 (1988), Nr. 8 | |
dc.rights | CC BY-NC-ND 3.0 Unported | |
dc.rights.uri | https://creativecommons.org/licenses/by-nc-nd/3.0/ | |
dc.subject | Bismutates | eng |
dc.subject | Crystal Structure | eng |
dc.subject | Lone Pair Electrons | eng |
dc.subject.ddc | 540 | Chemie | ger |
dc.title | Zur Stereochemie des freien Elektronenpaares in AX6E-Systemen, VIII Statisch verzerrte Anionen in [H3N(CH2)3NH3]3(BiX6)2(H2O)2 mit X = Cl, Br | ger |
dc.type | Article | |
dc.type | Text | |
dc.relation.essn | 1865-7117 | |
dc.relation.issn | 0932-0776 | |
dc.relation.doi | https://doi.org/10.1515/znb-1988-0815 | |
dc.bibliographicCitation.issue | 8 | |
dc.bibliographicCitation.volume | 43 | |
dc.bibliographicCitation.firstPage | 1003 | |
dc.bibliographicCitation.lastPage | 1009 | |
dc.description.version | publishedVersion | |
tib.accessRights | frei zug�nglich |
Die folgenden Lizenzbestimmungen sind mit dieser Ressource verbunden: