Hyperfine Structure in the Rotational Spectrum of GaBr

Abstract

The hyperfine structure of the rotational transition J = 2 ← 1 in the vicinity of 9.8 GHz was measured. The analysis yielded the following quadrupole coupling constants: e qv Q (79Br)= 105.78(34) + 0.92(38) (υ +1/2) MHz, e qv Q (81Br) = 88.55 (35) + 0.60 (32) (υ +1/2) MHz, e qv Q (69Ga) = − 86.68 (30) + 0.36 (24) (υ +1/2) MHz, e qv Q (71Ga) = − 54.58 (25) MHz. These results are consistent with systematic trends in the group of (III a/VII a) -compounds and remove some discrepencies in the literature. © 1978, Walter de Gruyter. All rights reserved.